1005769-62-9Relevant articles and documents
Catalytic Alkynylation of Polyfluoroarenes by Amide Base Generated In Situ
Shigeno, Masanori,Okawa, Takuya,Imamatsu, Masaya,Nozawa-Kumada, Kanako,Kondo, Yoshinori
, p. 10294 - 10297 (2019)
We herein demonstrate that the amide base generated in situ from CsF and N(TMS)3 catalyzes the deprotonative coupling reactions of terminal alkynes with polyfluoroarenes, wherein mono- and dialkynylations occur efficiently for penta- and hexafluorobenzenes, respectively. Tetraalkynylated products could also be synthesized from dialkynylated compounds.
Transition-metal-free synthesis of poly(phenylene ethynylene)s with alternating aryl-perfluoroaryl units
Dutta, Tanmoy,Woody, Kathy B.,Watson, Mark D.
, p. 452 - 453 (2008/09/19)
A catalytic amount of fluoride salt is all that is required to generate high molecular weight poly(phenylene ethynylene)s from silylacetylene-functionalized monomers and C6F6. The sole side product is gaseous fluorotrimethylsilane an