10099-66-8Relevant articles and documents
A structural variant to the NaErCl4/α-NiWO4 type for ternary rare-earth halides NaMCl4: Synthesis and crystal structure of NaLuCl4
Wickleder, Mathias S.,Güdel, Hans U.,Armbruster, Thomas,Meyer, Gerd
, p. 785 - 789 (1996)
Single crystals of NaLuCl4 (orthorhombic, Pbcn (Nr. 60), Z = 4, a = 618.6(1) pm, b = 1592.2(2) pm, c = 657.0(1) pm) were grown for the first time from the binary components using the Bridgman technique. The crystal structure may be derived from a hexagonally closest packing of Cl- spheres with one half of all octahedral sites occupied by the cations Na+ and Lu3+, respectively. The close relation of the structure to that of NaErCl4 (α-NiWO4) is discussed. NaScCl4 was found to be isotypic to NaLuCl4. Johann Ambrosius Barth 1996.
Self-assembled light lanthanide oxalate architecture with controlled morphology, characterization, growing mechanism and optical property
He, Hongmei,Zhang, Youjin,Zhu, Wei,Zheng, Ao
, p. 1546 - 1552 (2011/10/01)
Flower-like Sm2(C2O4)3· 10H2O had been synthesized by a facile complex agent assisted precipitation method. The flower-like Sm2(C2O 4)3·10H2O was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, thermogravimetry- differential thermal analysis and photoluminescence. The possible growth mechanism of the flower-like Sm2(C2O4) 3·10H2O was proposed. To extend this method, other Ln2(C2O4)3·nH2O (Ln = Gd, Dy, Lu, Y) with different morphologies also had been prepared by adjusting different rare earth precursors. Further studies revealed that besides the reaction conditions and the additive amount of complex agents, the morphologies of the as-synthesised lanthanide oxalates were also determined by the rare earth ions. The Sm2(C2O4) 3·10H2O and Sm2O3 samples exhibited different photoluminescence spectra, which was relevant to Sm 3+ energy level structure of 4f electrons. The method may be applied in the synthesis of other lanthanide compounds, and the work could explore the potential optical materials.
Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)
Ambrozini, B.,Dametto, P. R.,Ionashiro, M.
, p. 867 - 871 (2011/10/31)
Solid state Ln2-L3 compounds, where Ln stands for heavy trivalent lanthanides (terbium to lutetium) and yttrium, and L is tartrate [(C4H4O6)-2] have been synthesized. Simultaneous thermogra
Synthesis, characterization and thermal behaviour of heavy lanthanide and yttrium pyruvates in the solid state
Siqueira,De Carvalho,Rodrigues,Ionashiro,Bannach,Ionashiro
, p. 95 - 100 (2010/08/05)
Solid-state Ln-L compounds, where Ln stands for heavy trivalent lanthanides or yttrium (III) (Tb-Lu, Y) and where L is pyruvate, have been synthesized. Thermogravimetry and derivative thermogravimetry (TG/DTG), differential scanning calorimetry (DSC), X-R