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Cas Database

1011480-69-5

1011480-69-5

1011480-69-5

Identification

Synonyms:(((C6H5)COO)4Zn3(C4H8O)S)2

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Chemical Properties

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Relevant articles and documentsAll total 1 Articles be found

Alkylzinc carboxylates as efficient precursors for zinc oxocarboxylates and sulfidocarboxylates

Lewinski, Janusz,Bury, Wojciech,Dutkiewicz, Michal,Maurin, Michal,Justyniak, Iwona,Lipkowski, Janusz

, p. 573 - 576 (2008)

Zinc clusters: The first simple alkylzinc carboxylate provides insights into the previously unexplored oxygenation and sulfuration of alkylzinc complexes supported by carboxylate ligands (see picture). (Chemical Equation Presented).

Process route upstream and downstream products

Process route

tetrahydrofuran
109-99-9,24979-97-3,77392-70-2

tetrahydrofuran

sulfur
10544-50-0

sulfur

(Et-(zinc)-benzoate)6
1011480-68-4

(Et-(zinc)-benzoate)6

(((C<sub>6</sub>H<sub>5</sub>)COO)4Zn<sub>3</sub>(C<sub>4</sub>H<sub>8</sub>O)S)2
1011480-69-5

(((C6H5)COO)4Zn3(C4H8O)S)2

Conditions
Conditions Yield
In tetrahydrofuran; soln. of S8 in THF added to stirred soln. of (EtZn(O2CPh))6 in THF; after 2 d soln. concd.; stored at 0°C; crystals deposited after one d; elem. anal.; (1)H NMR, IR, XRD;
55%

1011480-69-5 Upstream products

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