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102-87-4

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102-87-4 Usage

Chemical Properties

Clear slightly yellow liquid. Soluble in organic solvents; insoluble in water. Combustible.

Uses

Different sources of media describe the Uses of 102-87-4 differently. You can refer to the following data:
1. Chemical intermediate, metal complexes.
2. TRIDODECYLAMINE (cas# 102-87-4) is a tertiary fatty amine which has been used in the preparation of an embedded telemetry system for potentiometric sensors, and in the preparation of gemini cationic surfactant-based ionic liquids.
3. Tridodecylamine(TDA) can be used in the following applications:Extraction of picolinic acid, citric acid, silver, mercury, selenium, zinc, cobalt, iron and succinic acid from aqueous solutions by using various organic solvents as diluents.Recovery of Remazol Red 3BS (R3BS) dye from wastewater via emulsion liquid membrane (ELM) process by using TDA as the carrier agent.Synthesis of gemini surfactant-based ionic liquids by reacting with dibromo alkanes.

General Description

Visit our Sensor Applications portal to learn more.

Purification Methods

Distil tridodecylamine under high vacuum and N2, and store it in the absence of CO2. It can be crystallised from 95%EtOH/*C6H6 at low temperature under vacuum. The hydrochloride has m 78-79o. [Ra et al. J Org Chem 9 259 1944, Beilstein 4 III 413, 4 IV 801.]

Check Digit Verification of cas no

The CAS Registry Mumber 102-87-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 2 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102-87:
(5*1)+(4*0)+(3*2)+(2*8)+(1*7)=34
34 % 10 = 4
So 102-87-4 is a valid CAS Registry Number.
InChI:InChI=1/C36H75N/c1-4-7-10-13-16-19-22-25-28-31-34-37(35-32-29-26-23-20-17-14-11-8-5-2)36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3

102-87-4 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
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  • Price
  • Detail
  • Alfa Aesar

  • (L04479)  Tri-n-dodecylamine, 95%   

  • 102-87-4

  • 10g

  • 377.0CNY

  • Detail
  • Alfa Aesar

  • (L04479)  Tri-n-dodecylamine, 95%   

  • 102-87-4

  • 50g

  • 1195.0CNY

  • Detail
  • Sigma-Aldrich

  • (95292)  HydrogenionophoreI  Selectophore, function tested

  • 102-87-4

  • 95292-100MG

  • 982.80CNY

  • Detail
  • Sigma-Aldrich

  • (95292)  HydrogenionophoreI  Selectophore, function tested

  • 102-87-4

  • 95292-500MG

  • 3,236.22CNY

  • Detail

102-87-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name TRIDODECYLAMINE

1.2 Other means of identification

Product number -
Other names N,N-didodecyldodecan-1-amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:102-87-4 SDS

102-87-4Synthetic route

n-Dodecylamine
124-22-1

n-Dodecylamine

A

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

B

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With Co2Rh2/C In toluene at 180℃; under 760.051 Torr; for 6h; Temperature; Time; Solvent; Autoclave; Inert atmosphere;A 86%
B 5%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h;A 26 % Chromat.
B 52%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h; Title compound not separated from byproducts;A 67 % Chromat.
B 30 % Chromat.
With tris(triphenylphosphine)ruthenium(II) chloride In methanol at 180℃; for 7h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
undecyl cyanide
2437-25-4

undecyl cyanide

A

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

B

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With hydrogen; silica gel; copper at 160℃; under 33002.6 Torr; for 2.69444h; Product distribution; Rate constant; other temperatures, other catalysts;A 84%
B n/a
With methanol; hydrogen at 249.9℃; under 37503 Torr; for 25h;A 15%
B 60 % Chromat.
With methanol; hydrogen; aluminum oxide; copper-chromium powder at 249.9℃; under 37503 Torr; for 25h;A 48 % Chromat.
B 5 % Chromat.
n-Dodecylamine
124-22-1

n-Dodecylamine

1-dodecylbromide
143-15-7

1-dodecylbromide

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With sodium carbonate In ethanol for 144h; Heating;22.6%
1-Iodododecane
4292-19-7

1-Iodododecane

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
at 160 - 170℃;
1-Iodododecane
4292-19-7

1-Iodododecane

A

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

B

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With ammonia; water
N,N-didodecylamine
3007-31-6

N,N-didodecylamine

1-chlorododecane
112-52-7

1-chlorododecane

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
at 160 - 170℃;
methanol
67-56-1

methanol

methyl n-dodecanoate
111-82-0

methyl n-dodecanoate

A

n-Dodecylamine
124-22-1

n-Dodecylamine

B

N,N-dimethylaminododecane
112-18-5

N,N-dimethylaminododecane

C

N-methyldodecylamine
7311-30-0

N-methyldodecylamine

D

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

E

N-methyldidodecylamine
2915-90-4

N-methyldidodecylamine

F

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr; Product distribution; other catalyst; var. temp., pressure, and reagents ratio;A 31.9 % Chromat.
B 20.0 % Chromat.
C 30.7 % Chromat.
D 2.5 % Chromat.
E 2.0 % Chromat.
F 2.0 % Chromat.
methyl n-dodecanoate
111-82-0

methyl n-dodecanoate

A

n-Dodecylamine
124-22-1

n-Dodecylamine

B

N,N-didodecylamine
3007-31-6

N,N-didodecylamine

C

tridodecylamine
102-87-4

tridodecylamine

Conditions
ConditionsYield
With methanol; ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr;A 31.9 % Chromat.
B 2.5 % Chromat.
C 2.0 % Chromat.
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

A

tridodecylamine
102-87-4

tridodecylamine

B

didodecylamine; dodecylamine

didodecylamine; dodecylamine

Conditions
ConditionsYield
With aluminium silicate; ammonia at 350℃;
tridodecyl-amine; compound with 2,4,6-trichloro-phenol

tridodecyl-amine; compound with 2,4,6-trichloro-phenol

A

tridodecylamine
102-87-4

tridodecylamine

B

2,4,6-Trichlorophenol
88-06-2

2,4,6-Trichlorophenol

Conditions
ConditionsYield
In tetrachloromethane at 25℃; Equilibrium constant;
tridodecyl-amine; compound with 2,4,6-trichloro-phenol

tridodecyl-amine; compound with 2,4,6-trichloro-phenol

A

tridodecylamine
102-87-4

tridodecylamine

B

2,4,6-Trichlorophenol
88-06-2

2,4,6-Trichlorophenol

Conditions
ConditionsYield
In tetrachloromethane at 25℃; Equilibrium constant;
tridodecylamine
102-87-4

tridodecylamine

tridodecylamine oxide
20587-64-8

tridodecylamine oxide

Conditions
ConditionsYield
With dihydrogen peroxide In methanol; water85%
tridodecylamine
102-87-4

tridodecylamine

undecyl cyanide
2437-25-4

undecyl cyanide

Conditions
ConditionsYield
With ammonium hydroxide; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione at 60℃; for 6h;84%
With ammonium hydroxide; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione at 60℃; for 6h;84%
C22H17Cl2N2O5S(1-)*K(1+)
937802-88-5

C22H17Cl2N2O5S(1-)*K(1+)

tridodecylamine
102-87-4

tridodecylamine

C22H18Cl2N2O5S*C36H75N
937802-92-1

C22H18Cl2N2O5S*C36H75N

Conditions
ConditionsYield
With hydrogenchloride In methanol; water at 70℃; for 0.25h;83%
tridodecylamine
102-87-4

tridodecylamine

N,N-didodecylformamide

N,N-didodecylformamide

Conditions
ConditionsYield
With manganese(IV) oxide; oxygen In chlorobenzene at 100℃; under 4500.45 Torr; for 4h; Autoclave; Green chemistry;80%
tridodecylamine
102-87-4

tridodecylamine

4-bromomethyl-4'-methacrylamidocarbonylazobenzene

4-bromomethyl-4'-methacrylamidocarbonylazobenzene

C54H91N4O2(1+)*Br(1-)

C54H91N4O2(1+)*Br(1-)

Conditions
ConditionsYield
In ethanol for 10h; Reflux;73.5%
tridodecylamine
102-87-4

tridodecylamine

C46H28N6O8

C46H28N6O8

europium(III) nitrate

europium(III) nitrate

C46H24N6O8(4-)*Eu(3+)*C36H75N*H(1+)

C46H24N6O8(4-)*Eu(3+)*C36H75N*H(1+)

Conditions
ConditionsYield
In methanol at 20℃; for 4h; Inert atmosphere;67.3%
1,3-propanesultone
1120-71-4

1,3-propanesultone

tridodecylamine
102-87-4

tridodecylamine

tridodecylammonium 3-propanesulfonate
103982-08-7

tridodecylammonium 3-propanesulfonate

Conditions
ConditionsYield
In toluene at 110℃; for 3h;62%
tridodecylamine
102-87-4

tridodecylamine

benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

benzaldehyde
100-52-7

benzaldehyde

5-decyl-2,4-diphenylpyrimidine

5-decyl-2,4-diphenylpyrimidine

Conditions
ConditionsYield
With di-tert-butyl peroxide; iodine In chlorobenzene at 150℃; for 8h;62%
With di-tert-butyl peroxide; iodine In chlorobenzene at 150℃; for 8h; Sealed tube;62%
C24H19N2O5S(1-)*K(1+)

C24H19N2O5S(1-)*K(1+)

tridodecylamine
102-87-4

tridodecylamine

C24H20N2O5S*C36H75N

C24H20N2O5S*C36H75N

Conditions
ConditionsYield
With hydrogenchloride; water61%
methyl bromide
74-83-9

methyl bromide

tridodecylamine
102-87-4

tridodecylamine

tridodecylmethylammonium chloride
29920-02-3

tridodecylmethylammonium chloride

Conditions
ConditionsYield
In ethanol at 90 - 95℃; for 183h;52%
furfural
98-01-1

furfural

tridodecylamine
102-87-4

tridodecylamine

para-iodoanisole
696-62-8

para-iodoanisole

C32H57NO2

C32H57NO2

Conditions
ConditionsYield
With Wilkinson’s catalyst; 1,3-bis-(diphenylphosphino)propane; water In tetrahydrofuran at 140℃; for 12h; Inert atmosphere; Sealed tube;52%
tridodecylamine
102-87-4

tridodecylamine

α-bromoacetophenone
70-11-1

α-bromoacetophenone

3-decyl-N,N-didodecyl-5-phenylfuran-2-amine

3-decyl-N,N-didodecyl-5-phenylfuran-2-amine

Conditions
ConditionsYield
With [2,2]bipyridinyl; iron(III) chloride; di-tert-butyl peroxide In toluene at 135℃; for 14h; Sealed tube;40%
zinc perchlorate

zinc perchlorate

tridodecylamine
102-87-4

tridodecylamine

C44H28N6O4
1439241-70-9

C44H28N6O4

europium(III) nitrate

europium(III) nitrate

2C44H26N6O4(2-)*Eu(3+)*Zn(2+)*2ClO4(1-)*C36H75N*H(1+)

2C44H26N6O4(2-)*Eu(3+)*Zn(2+)*2ClO4(1-)*C36H75N*H(1+)

Conditions
ConditionsYield
Stage #1: tridodecylamine; C44H28N6O4; europium(III) nitrate In methanol at 20℃; for 4h;
Stage #2: zinc perchlorate In methanol at 20℃; for 1h; Concentration;
36.9%
iron(II) tetrafluoroborate

iron(II) tetrafluoroborate

tridodecylamine
102-87-4

tridodecylamine

C44H28N6O4
1439241-70-9

C44H28N6O4

europium(III) nitrate

europium(III) nitrate

2C44H26N6O4(2-)*C36H76N(1+)*Eu(3+)*Fe(2+)*2BF4(1-)

2C44H26N6O4(2-)*C36H76N(1+)*Eu(3+)*Fe(2+)*2BF4(1-)

Conditions
ConditionsYield
Stage #1: tridodecylamine; C44H28N6O4; europium(III) nitrate In methanol at 20℃; for 1h;
Stage #2: iron(II) tetrafluoroborate In methanol at 20℃; for 1h;
35.8%
hydroxygallium naphthalocyaninetetrasulfonic acid

hydroxygallium naphthalocyaninetetrasulfonic acid

tridodecylamine
102-87-4

tridodecylamine

4C36H75N*C48H25GaN8O13S4

4C36H75N*C48H25GaN8O13S4

Conditions
ConditionsYield
In methanol; water32%
tridodecylamine
102-87-4

tridodecylamine

S,S'-diethyl-S,S'-dimethyl-S,S'-cis-ethene-1,2-diyl-bis-sulfonium; bis-tetrafluoroborate

S,S'-diethyl-S,S'-dimethyl-S,S'-cis-ethene-1,2-diyl-bis-sulfonium; bis-tetrafluoroborate

C41H85NS(2+)*2BF4(1-)

C41H85NS(2+)*2BF4(1-)

tridodecylamine
102-87-4

tridodecylamine

methyl iodide
74-88-4

methyl iodide

tri-n-dodecylmethylammonium iodide
29710-98-3

tri-n-dodecylmethylammonium iodide

Conditions
ConditionsYield
for 24h; Heating;
tridodecylamine
102-87-4

tridodecylamine

tri-n-dodecylammonium chloride
2486-89-7

tri-n-dodecylammonium chloride

Conditions
ConditionsYield
With hydrogenchloride In water
tridodecylamine
102-87-4

tridodecylamine

tridodecylamine; nitrate
2305-34-2

tridodecylamine; nitrate

Conditions
ConditionsYield
With nitric acid In water
tridodecylamine
102-87-4

tridodecylamine

2,4,6-Trichlorophenol
88-06-2

2,4,6-Trichlorophenol

tridodecyl-amine; compound with 2,4,6-trichloro-phenol

tridodecyl-amine; compound with 2,4,6-trichloro-phenol

Conditions
ConditionsYield
In tetrachloromethane at 25℃; Equilibrium constant;

102-87-4Related news

Extraction equilibria of picolinic acid from aqueous solution by TRIDODECYLAMINE (cas 102-87-4) (TDA)08/13/2019

Pyridine compounds having a carboxyl side chain at the 2-position are attracting considerable attention for their ability. Chromium, manganese, iron, copper, zinc, and molybdenum are present as chelating agents in the human body. Picolinic acid acts as a chelating agent instead of these elements...detailed

LSER modeling of extraction of succinic acid by TRIDODECYLAMINE (cas 102-87-4) dissolved in 2-octanone and 1-octanol08/12/2019

Reactive extraction can be used for the recovery of carboxylic acids from fermentation broth. Through the formation of complex with extractants at the two-phase interface, the carboxylic acids are partitioned into organic solvents. But, the recovery of carboxylic acids is interrupted by the cond...detailed

102-87-4Relevant articles and documents

Selectivity control in substituted fatty amines synthesis from esters or nitriles in the presence of bifunctional catalysts

Barrault,Brunet,Suppo-Essayem,Piccirilli,Guimon

, p. 1231 - 1238 (1994)

Copper chromite-type catalysts, supported by alumina or graphite and promoted with barium, were used for the one-step synthesis of tertiary fatty amines [R2NCH3 or RN(CH3)2] from ester, acid or nitrile and ammonia, methanol and hydrogen. The surface composition of the catalysts, studied by X-ray photoelectron spectroscopy and by adsorption experiments, showed that there was a correlation between selectivity and the presence of a well-dispersed CuCrO2 phase, stabilized with barium. Moreover, the elements influencing the stability of the copper catalysts were also studied, and the promoter or/and the support increased the copper surface area and the stability of the catalyst in the presence of water or ammonia.

Alkyl substituent effect on the polarity of phenols-tri-n-alkylamine complexes

Pawelka, Zbigniew,Zeegers-Huyskens, Therese

, p. 1012 - 1018 (2007/10/03)

The formation constants and the dipole moments of the H-bonded adducts of 1:1 and 2:1 stoichiometries formed between three different phenols (phenol, 2,4,6-trichlorophenol, and 2,4-dinitrophenol) and different tri-n-alkylamines are determined in solvents

Amine oxide process

-

, (2008/06/13)

A process for accelerating the oxidation of tert-amines by hydrogen peroxide by conducting the reaction in the presence of an ascorbic acid promoter.

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