1020108-62-6

Basic information

• Product Name: 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol
• Synonyms: 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol
• CAS NO: 1020108-62-6
• Molecular Weight: 256.388
• Mol File: 1020108-62-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol(1020108-62-6)
• EPA Substance Registry System: 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol(1020108-62-6)

Safety Data

• Hazardous Substances Data: 1020108-62-6(Hazardous Substances Data)

Upstream product

• 1020108-61-5 (R,E)-1-(3,7-dimethyl-3-vinylocta-1,6-dien-1-yl)-4-methoxybenzene 
• 17015-63-3 (S,E)-1-(3,7-dimethyl-3-vinylocta-1,6-dien-1-yl)-4-methoxybenzene 
• 80-59-1 Tiglic acid 
• 1020108-59-1 (2S)-2-[(E)-2-(4-methoxyphenyl)ethenyl]-2,6-dimethylhept-5-en-1-ol 
• 1492057-09-6 C₃₄H₄₄O₂Si 
• 1492057-03-0 C₂₇H₃₈OSi 
• 1492057-02-9 (S)-((2-(2-bromoethyl)-2-methylbut-3-en-1-yl)oxy)(tert-butyl)diphenylsilane 
• 1492057-01-8 (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol 
• 1492056-99-1 (S)-tert-butyl 3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-enoate 
• 1492056-88-8 (S)-tert-butyl 3-(hydroxymethyl)-3-methylpent-4-enoate 
• 1020108-60-4 (2S)-2-[(E)-2-(4-methoxyphenyl)ethenyl]-2,6-dimethylhept-5-enal 
• 1492056-85-5 (S)-tert-butyl 3-((R)-4-isopropyl-2-oxooxazolidine-3-carbonyl)-3-methylpent-4-enoate 
• 35660-94-7 (E)-2-methylbut-2-enoyl chloride 

Relevant articles and documents

A facile asymmetric synthesis of Δ3-2-Hydroxybakuchiol, Bakuchiol and ent-Bakuchiol

A facile asymmetric synthesis of Δ3-2-Hydroxybakuchiol, Bakuchiol, and ent-Bakuchiol is described through one common intermediate bearing a chiral all-carbon quaternary carbon center, which involves stereoselectively unconjugated alkylation of the α,β-unsaturated imide bearing Evans' auxiliary, Takai-Utimoto reaction, Negishi reaction, and Heck reaction as key steps.

Stereoselective total synthesis of natural (S)-bakuchiol and its enantiomer

A practical stereoselective synthesis of (S)-bakuchiol (1) and its enantiomer is reported. The important intermediate, (R)-configured β-siloxy aldehyde 5, was obtained in three steps from the easily available material geraniol (2) via the key step of Yamamoto's rearrangement of epoxy silyl ethers. (S)-Bakuchiol (1) and its enantiomer, (R)-bakuchiol (17), were finally obtained in different synthetic sequences with overall yields of 51% (ten steps) and 40% (nine steps) from geraniol (2), respectively.