102475-76-3

Basic information

• Product Name: (3R,4R,5S)-2-(acetoxymethyl)-6-(4-acetylphenyl)tetrahydro-2H-pyran-3,4,5-triyltriacetate
• Synonyms: (3R,4R,5S)-2-(acetoxymethyl)-6-(4-acetylphenyl)tetrahydro-2H-pyran-3,4,5-triyltriacetate
• CAS NO: 102475-76-3
• Molecular Weight: 450.442
• Mol File: 102475-76-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3R,4R,5S)-2-(acetoxymethyl)-6-(4-acetylphenyl)tetrahydro-2H-pyran-3,4,5-triyltriacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5S)-2-(acetoxymethyl)-6-(4-acetylphenyl)tetrahydro-2H-pyran-3,4,5-triyltriacetate(102475-76-3)
• EPA Substance Registry System: (3R,4R,5S)-2-(acetoxymethyl)-6-(4-acetylphenyl)tetrahydro-2H-pyran-3,4,5-triyltriacetate(102475-76-3)

Safety Data

• Hazardous Substances Data: 102475-76-3(Hazardous Substances Data)

Upstream product

• 13329-40-3 4-Iodoacetophenone 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 506-96-7 Acetyl bromide 
• 13231-13-5 (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene 

Relevant articles and documents

Stereoselective Preparation of α- C-Vinyl/Aryl Glycosides via Nickel-Catalyzed Reductive Coupling of Glycosyl Halides with Vinyl and Aryl Halides

Facile preparation of the α-C-vinyl and -aryl glycosides has been developed via mild Ni-catalyzed reductive vinylation and arylation of C1-glycosyl halides with vinyl/aryl halides. Good to high α-selectivities were achieved for C-glucosides, galactosides, maltoside, and mannosides, which were dictated by the employment of pyridine type ligands. As such, the present work represents unprecedented control for a high level of α-selectivity for C-vinyl-glucosides using cross-coupling approaches and offers hitherto optimal α-selective preparation of C-aryl glucosides via catalyst-controlled coupling strategies.