10359-36-1

Basic information

• Product Name: 4-NITROPHENYLDIPHENYLPHOSPHATE
• Synonyms: 4-NITROPHENYLDIPHENYLPHOSPHATE;Phosphoric acid diphenyl p-nitrophenyl ester;Phosphoric acid diphenyl(4-nitrophenyl) ester;Phosphoric acid diphenyl=(4-nitrophenyl) ester;Phosphoric acid diphenyl=4-nitrophenyl ester;Phosphoric acid p-nitrophenyldiphenyl ester
• CAS NO: 10359-36-1
• Molecular Formula: C₁₈H₁₄NO₆P
• Molecular Weight: 0
• Mol File: 10359-36-1.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 456.1°Cat760mmHg
• Flash Point: 229.6°C
• Appearance: /
• Density: 1.376g/cm³
• Vapor Pressure: 4.51E-08mmHg at 25°C
• Refractive Index: 1.615
• CAS DataBase Reference: 4-NITROPHENYLDIPHENYLPHOSPHATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-NITROPHENYLDIPHENYLPHOSPHATE(10359-36-1)
• EPA Substance Registry System: 4-NITROPHENYLDIPHENYLPHOSPHATE(10359-36-1)

Safety Data

• Hazardous Substances Data: 10359-36-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H14NO6P/c20-19(21)15-11-13-18(14-12-15)25-26(22,23-16-7-3-1-4-8-16)24-17-9-5-2-6-10-17/h1-14H

Upstream product

• 100-02-7 4-nitro-phenol 
• 838-85-7 diphenyl hydrogen phosphate 
• 1124-32-9 lithium 4-nitrophenolate 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 777-52-6 1-dichlorophosphoryloxy-4-nitro-benzene 
• 108-95-2 phenol 
• 681035-22-3 (2-oxo-5,5-diphenyl-oxazolidin-3-yl)-phosphonic acid diphenyl ester 

Downstream Products

• 155791-59-6 Phosphoric acid 3-oxo-3H-1λ³-benzo[d][1,2]iodoxol-1-yl ester diphenyl ester 
• 14609-74-6 p-nitrophenolate 
• 115-86-6 phosphoric acid triphenyl ester 
• 56961-58-1 4-chlorophenyl diphenyl phosphate 
• 60586-07-4 p-Acetylphenyldiphenylphosphat 
• 60586-03-0 4-cyanophenyl diphenyl phosphate 
• 187804-69-9 4-formylphenyl diphenyl phosphate 
• 28469-85-4 Phosphoric acid 2,4-dichloro-phenyl ester diphenyl ester 
• 115-85-5 2-chlorophenyl diphenyl phosphate 
• 59616-64-7 pentafluorophenyl diphenyl phosphate 

Relevant articles and documents

A simple and effective method for phosphoryl transfer using TiCl4 catalysis

(graph presented) A number of Lewis acids have been evaluated as catalysts for the phosphoryl transfer, the most efficient being TiCl4. Application of this methodology to the phosphorylation of a number of representative target alcohols is presented.

Enhanced catalytic decomposition of a phosphate triester by modularly accessible bimetallic porphyrin dyads and dimers

A series of metalloporphyrin dimers were modularly prepared and shown to catalyze the methanolysis of a phosphate triester, yielding rates that are large compared to the rate of the uncatalyzed reaction. Up to 1300-fold rate acceleration can be achieved v

Substitution- and elimination-free phosphorylation of functionalized alcohols catalyzed by oxidomolybdenum tetrachloride

Among 14 oxidometallic species examined for catalytic phosphorylation of the tested alcohols, oxidomolybdenum tetrachloride (MoOCl4) was found to be the most efficient with a negligible background reaction mediated by triethylamine (Et3N). The new catalytic protocol can be applied to the chemoselective phosphorylations of primary, secondary and tertiary alcohols as well as the substitution-free phosphorylations of allylic, propargylic, and benzylic alcohols. Functionalized alcohols bearing acetonide, tetrahydropyranyl ether, tert-butyldimethylsilyl ether, or ester group are also amenable to the new catalytic protocol. The most difficult scenarios involve substitution-free phosphorylations of 1-phenylethanol and 1-(2-naphthyl)ethanol which can be effected in 95 and 90% yields, respectively. ESI-MS, IR, 1H, and 31P NMR spectroscopic analyses of the reaction progress suggest the intermediacy of an alkoxyoxidomolybdenum trichloride-triethylamine adduct such as [(RO)Mo(O)Cl3-Et3N] to be responsible for the catalytic turnover.