1039307-84-0Relevant articles and documents
Simple protocol for the synthesis of the asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3- (CH(CH3)PPh2)] and its Pd(II) derivative [PdCl{C6H3-2-(CH2PPh2)-6- (CH(CH3)PPh2)}]
Naghipour, Ali,Ghasemi, Zahra Haji,Morales-Morales, David,Serrano-Becerra, Juan M.,Jensen, Craig M.
, p. 1947 - 1952 (2008)
The asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH (CH3)PPh2)] (4) has been synthesized in a facile manner in three simple steps in high yield. Metallation of PCP pincer ligand (4) with [Pd(COD)Cl2] affords complex [PdCl{C6H3-2-(CH2PPh2)-6-(CH (CH3)PPh2)}] (7) in good yield.