10428-50-9

Basic information

• Product Name: N,N-di(pyridin-2-yl)pyridin-2-amine
• CAS NO: 10428-50-9
• Molecular Formula: C₁₅H₁₂N₄
• Molecular Weight: 248.2826
• Mol File: 10428-50-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 427.2°C at 760 mmHg
• Flash Point: 212.2°C
• Density: 1.239g/cm³
• Vapor Pressure: 1.67E-07mmHg at 25°C
• Refractive Index: 1.664
• CAS DataBase Reference: N,N-di(pyridin-2-yl)pyridin-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-di(pyridin-2-yl)pyridin-2-amine(10428-50-9)
• EPA Substance Registry System: N,N-di(pyridin-2-yl)pyridin-2-amine(10428-50-9)

Safety Data

• Hazardous Substances Data: 10428-50-9(Hazardous Substances Data)

Upstream product

• 504-29-0 2-aminopyridine 
• 5029-67-4 2-iodopyridine 
• 109-04-6 2-bromo-pyridine 
• 1202-34-2 di(pyridin-2-yl)amine 

Downstream Products

• 114466-50-1 bis{tris(2-pyridyl)amine}ruthenium(II) tosylate 
• 1627578-47-5 C₂₁H₁₉MoN₄O₂⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-) 
• 178320-17-7 [ReO(OCH₂CH₂O)(PPh₃)(tri-2-pyridylamine)]Cl 
• 178320-14-4 [IrH2(PPh3)2(η(2)-tri-2-pyridylamine)]BF4 

Relevant articles and documents

Ruthenium(II) η6-arene complexes containing a dinucleating ligand based on 1,8-naphthyridine

Ruthenium arene complexes, [(η6-p-cymene)2Ru2(L)Cl2](PF6)2 [3b, L = 2, 7-bis(di-2-pyridinyl)-1,8-naphthyridine] and [(η6-p-cymene)Ru(L′)Cl](PF6) [4, L′ = tri(2-pyridinyl)amine], were synthesized and characterized by spectroscopic and analytical techniques. The molecular structure of [(η6-p-cymene)2Ru2(L)Cl2]Cl2 (3a) was further determined by single-crystal X-ray analysis. The use of these ruthenium complexes as pre-catalysts for oxidative coupling of 1,2-diols/1,2-aminoalcohol with o-phenylenediamines leading to quinoxalines was investigated. Complex 3b appeared to be a good catalyst for this transformation.

Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system

The one-pot synthesis of symmetrical or unsymmetrical di- or triarylamines using aryl iodides or bromides and LiNH2 as ammonia source is reported. This highly selective method is based, for the first time, on a copper-catalyzed system, which does not require the presence of any additional ligand.