1043913-35-4

Basic information

• Product Name: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(C₄H₄O₄)]
• Synonyms: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(C₄H₄O₄)]
• CAS NO: 1043913-35-4
• Molecular Weight: 776.884
• Mol File: 1043913-35-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(C₄H₄O₄)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(C₄H₄O₄)](1043913-35-4)
• EPA Substance Registry System: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(C₄H₄O₄)](1043913-35-4)

Safety Data

• Hazardous Substances Data: 1043913-35-4(Hazardous Substances Data)

Upstream product

• 17013-01-3 fumaric acid disodium salt 

Downstream Products

• 624-49-7 dimethylfumarate 

Relevant articles and documents

Unusual hydrogenation of fumarate anion followed by metal-carbon bond formation: Synthesis and characterization of two metallochelates

The treatment of [M(dppf)(H2O)2](OTf)2 (dppf =1,1′-bis(diphenylphosphino)ferrocene; M = Pd, Pt) with 1 equiv of disodium fumarate in methanol medium showed an unusual hydrogenation of the ethylenic bond followed by the formation of metallochelates linking M through one of the carboxylates and the β-carbon with respect to COO-. Despite the possibility of formation of a [2 + 2] or [4 + 4] self-assembled macrocycle, the reduction of fumarate to succinate, and in particular the linking through the β-carbon, is unique since a similar treatment using disodium succinate instead of disodium fumarate yielded an expected metallochelate where both the carboxylates were coordinated to the square-planar metal.