1048329-91-4Relevant articles and documents
The Catalyst-Controlled Divergent Cascade Reactions of Homo-Propargylic Amines and Nitrones: Synthesis of Pyrrolo-Isoxazolidines and γ-Lactams
Kong, Yuanfang,Liu, Yingze,Wang, Boyi,Li, Shengli,Liu, Lingyan,Chang, Weixing,Li, Jing
, p. 1240 - 1252 (2018/02/21)
Two controllable one-pot cascade cyclization reactions of homopropargylic amines and nitrones were developed by using different metal Cu and Ag salts. The pyrroloisoxazolidines and γ-lactams were obtained in good to high yields, respectively. Herein, nitr
Highly efficient and versatile synthesis of lactams and N -heterocycles via Al(OTf)3-catalyzed cascade cyclization and ionic hydrogenation reactions
Qi, Jianguo,Sun, Chenbin,Tian, Yulin,Wang, Xiaojian,Li, Gang,Xiao, Qiong,Yin, Dali
supporting information, p. 190 - 192 (2014/01/23)
The discovery and development of an efficient and versatile method for the synthesis of N-substituted lactams is described. Pyrrolindinones, piperidones, and structurally related heterocycles were formed by Al(OTf)3- catalyzed cascade cyclizati
Regioselective synthesis of γ-amino esters, nitriles, sulfones, and pyrrolidinones by nickel-catalyzed reductive coupling of aldimines and activated alkenes
Yeh, Chien-Hung,Korivi, Rajendra Prasad,Cheng, Chien-Hong
supporting information; experimental part, p. 4892 - 4895 (2009/02/08)
(Chemical Equation Presented) A couple of alternatives: An efficient method has been developed for the synthesis of γ-amino derivatives and pyrrolidinones from readily available starting materials by using a nickel-phenanthroline complex (see scheme). The reaction proceeds by the formation of a C-C bond at the β-carbon atom, instead of the more usual α-carbon atom, of a conjugated alkene via an azanickelacycle intermediate.
