10516-92-4Relevant articles and documents
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Eisch et al.
, p. 4575 (1969)
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Palladium-catalyzed cross-coupling of styrenes with aryl methyl ketones in ionic liquids: Direct access to cyclopropanes
Cotugno, Pietro,Monopoli, Antonio,Ciminale, Francesco,Milella, Antonella,Nacci, Angelo
, (2014)
The combined use of Pd(OAc)2, Cu(OAc)2, and dioxygen in molten tetrabutylammonium acetate (TBAA) promotes an unusual cyclopropanation reaction between aryl methyl ketones and styrenes. The process is a dehydrogenative cyclizing coupl
Copper-catalyzed base-accelerated direct oxidation of C-H bond to synthesize benzils, isatins, and quinoxalines with molecular oxygen as terminal oxidant
Yu, Jing-Wen,Mao, Shuai,Wang, Yong-Qiang
, p. 1575 - 1580 (2015/03/14)
We describe herein an efficient and general copper (II)-catalyzed base-accelerated oxidation of the C-H bond to synthesize benzils and isatins. With similar oxidation system an efficient one-pot procedure for the synthesis of quinoxaline derivatives was realized. The two protocols feature using molecular oxygen as terminal oxidant, low catalyst loading, wide substrate scope, and high functional-group tolerance.
Chemoselective oxidative C(CO)-C(methyl) bond cleavage of methyl ketones to aldehydes catalyzed by CuI with molecular oxygen
Zhang, Lin,Bi, Xihe,Guan, Xiaoxue,Li, Xingqi,Liu, Qun,Barry, Badru-Deen,Liao, Peiqiu
supporting information, p. 11303 - 11307 (2013/11/06)
Aldehyde Termination: A novel copper-catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide range of aromatic and aliphatic methyl ketones and chemoselectively produces aldehydes, accompanied by the release of hydrogen (H2) and carbon dioxide (CO2) as by-products. Copyright