Welcome to LookChem.com Sign In|Join Free

CAS

  • or

10563-26-5

Post Buying Request

10563-26-5 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

10563-26-5 Usage

Chemical Properties

CLEAR COLOURLESS TO PALE YELLOW LIQUID

General Description

The condensation reaction of 1,2-bis(3-aminopropylamino)ethane [3,3′-ethylenediiminodipropylamine] with 4,6-dibenzofurandicarbaldehyde was studied.

Hazard

A poison by skin contact.Moderately toxic by ingestion.

Flammability and Explosibility

Nonflammable

Safety Profile

A poison by skin contact. Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx.

Check Digit Verification of cas no

The CAS Registry Mumber 10563-26-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,5,6 and 3 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 10563-26:
(7*1)+(6*0)+(5*5)+(4*6)+(3*3)+(2*2)+(1*6)=75
75 % 10 = 5
So 10563-26-5 is a valid CAS Registry Number.

10563-26-5 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (B1952)  N,N'-Bis(3-aminopropyl)ethylenediamine  >98.0%(GC)(T)

  • 10563-26-5

  • 25mL

  • 99.00CNY

  • Detail
  • TCI America

  • (B1952)  N,N'-Bis(3-aminopropyl)ethylenediamine  >98.0%(GC)(T)

  • 10563-26-5

  • 500mL

  • 620.00CNY

  • Detail
  • Aldrich

  • (239399)  1,2-Bis(3-aminopropylamino)ethane  technical grade, 94%

  • 10563-26-5

  • 239399-100ML

  • 355.68CNY

  • Detail

10563-26-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3,2,3-tetramine

1.2 Other means of identification

Product number -
Other names N'-[2-(3-aminopropylamino)ethyl]propane-1,3-diamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. CBI,Intermediates
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10563-26-5 SDS

10563-26-5Synthetic route

(4aS,4bR)-4a-Phenyl-dodecahydro-4,5,8a,10a-tetraaza-phenanthrene

(4aS,4bR)-4a-Phenyl-dodecahydro-4,5,8a,10a-tetraaza-phenanthrene

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With hydrogenchloride In water at 70℃; for 2h;90%
ethylenediamine
107-15-3

ethylenediamine

acrylonitrile
107-13-1

acrylonitrile

A

N,N,N'-tris(3-aminopropyl)ethylenediamine
79506-61-9

N,N,N'-tris(3-aminopropyl)ethylenediamine

B

N-(2-Aminoethyl)-1,3-propanediamine
13531-52-7

N-(2-Aminoethyl)-1,3-propanediamine

C

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

D

N,N,N',N'-tetrakis(3-aminopropyl)ethylenediamine
4879-98-5

N,N,N',N'-tetrakis(3-aminopropyl)ethylenediamine

Conditions
ConditionsYield
Stage #1: ethylenediamine; acrylonitrile In water at 60℃; for 6.5h;
Stage #2: With hydrogen In water; isopropyl alcohol at 120℃; under 41254.1 Torr; for 5h; Inert atmosphere;
A 11%
B 6%
C 80%
D 2%
(10-methyl-10-nitro-1,4,8,12-tetraazacyclopentadecane)copper(II) nitrate

(10-methyl-10-nitro-1,4,8,12-tetraazacyclopentadecane)copper(II) nitrate

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With H2S In water H2S is bubbled through an aq. soln. of the complex for 20 min, .; Filtn., the colourless filtrate is evapd. to dryness, the viscous gum yields a withe solid on trituration with EtOH, chromy. (Dowex H(1+)-form, HCl).;70%
di-tert-butyl ethane-1,2-diylbis((3-(2-(4-((E)-phenyldiazenyl)phenoxy)acetamido)propyl)carbamate)

di-tert-butyl ethane-1,2-diylbis((3-(2-(4-((E)-phenyldiazenyl)phenoxy)acetamido)propyl)carbamate)

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With acetyl chloride In methanol at 0 - 20℃; for 29h;50%
N,N'-bis-(2-cyanoethyl)ethylenediamine
3217-00-3

N,N'-bis-(2-cyanoethyl)ethylenediamine

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With ammonia; hydrogen; nickel In ethanol
ethylene dibromide
106-93-4

ethylene dibromide

Trimethylenediamine
109-76-2

Trimethylenediamine

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

3,8-dioxo-4,7-diazadecanediamide
36394-60-2

3,8-dioxo-4,7-diazadecanediamide

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran for 7h; Heating;
N-[2-(2-methoxycarbonyl-acetylamino)-ethyl]-malonamic acid methyl ester
477808-21-2

N-[2-(2-methoxycarbonyl-acetylamino)-ethyl]-malonamic acid methyl ester

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NH3 / methanol / 7 °C
2: BH3*THF / tetrahydrofuran / 7 h / Heating
View Scheme
N,N'-bis-(2-cyanoethyl)ethylenediamine
3217-00-3

N,N'-bis-(2-cyanoethyl)ethylenediamine

N,N,N'-tris(2-cyanoethyl)-1,2-ethylenediamine
56576-72-8

N,N,N'-tris(2-cyanoethyl)-1,2-ethylenediamine

N-(β-cyanoethyl)ethylenediamine
22584-31-2

N-(β-cyanoethyl)ethylenediamine

A

N,N,N'-tris(3-aminopropyl)ethylenediamine
79506-61-9

N,N,N'-tris(3-aminopropyl)ethylenediamine

B

N-(2-Aminoethyl)-1,3-propanediamine
13531-52-7

N-(2-Aminoethyl)-1,3-propanediamine

C

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
With ammonia; hydrogen; Raney cobalt 2724 at 75 - 80℃; under 20627.1 Torr; for 4.5h; Product distribution / selectivity;
With hydrogen; Raney cobalt 2724 In isopropyl alcohol at 120℃; under 42133 Torr; for 4h; Product distribution / selectivity;
With hydrogen; lithium hydroxide In water; isopropyl alcohol at 120℃; under 26252.6 - 41254.1 Torr; for 4.16667h; Product distribution / selectivity;
With hydrogen; lithium hydroxide In water at 70 - 80℃; under 20627.1 Torr; Product distribution / selectivity;
With hydrogen; lithium hydroxide at 120℃; under 26252.6 - 41254.1 Torr; for 4.08333h; Product distribution / selectivity;
(3α,5β)-3,24-bis(3-bromophenoxy)cholane
874306-28-2

(3α,5β)-3,24-bis(3-bromophenoxy)cholane

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

N-[2-(3-Amino-propylamino)-ethyl]-N'-(3-{(R)-4-[(3S,5R,8R,9S,10S,13R,14S,17R)-3-(3-{3-[2-(3-amino-propylamino)-ethylamino]-propylamino}-phenoxy)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-yl]-pentyloxy}-phenyl)-propane-1,3-diamine

N-[2-(3-Amino-propylamino)-ethyl]-N'-(3-{(R)-4-[(3S,5R,8R,9S,10S,13R,14S,17R)-3-(3-{3-[2-(3-amino-propylamino)-ethylamino]-propylamino}-phenoxy)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-yl]-pentyloxy}-phenyl)-propane-1,3-diamine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane Heating;100%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; [Pd(dibenzylideneacetone)2] In 1,4-dioxane for 5h; Heating;90 % Spectr.
2-chloro-4,6-bis-((2,2,6,6-tetramethyl-piperidin-4-yl)butylamino)-1,3,5-triazine

2-chloro-4,6-bis-((2,2,6,6-tetramethyl-piperidin-4-yl)butylamino)-1,3,5-triazine

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1, 5,8,12-tetraazadodecane

1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1, 5,8,12-tetraazadodecane

Conditions
ConditionsYield
With sodium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene at 180℃; for 12h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;96.5%
ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

2,2,2-Trifluoro-N-(3-{2-[3-(2,2,2-trifluoro-acetylamino)-propylamino]-ethylamino}-propyl)-acetamide
181181-34-0

2,2,2-Trifluoro-N-(3-{2-[3-(2,2,2-trifluoro-acetylamino)-propylamino]-ethylamino}-propyl)-acetamide

Conditions
ConditionsYield
In tetrahydrofuran Ambient temperature;96%
In dichloromethane at 0 - 20℃; for 1.5h;
In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;
ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

2,2,2-Trifluoro-N-[3-(2,2,2-trifluoro-acetylamino)-propyl]-N-{2-[3-(2,2,2-trifluoro-acetylamino)-propylamino]-ethyl}-acetamide
181181-35-1

2,2,2-Trifluoro-N-[3-(2,2,2-trifluoro-acetylamino)-propyl]-N-{2-[3-(2,2,2-trifluoro-acetylamino)-propylamino]-ethyl}-acetamide

Conditions
ConditionsYield
In tetrahydrofuran Ambient temperature;96%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

4-({3-[2-(3-amino-propylamino)-ethylamino]-propylamino}-methyl)-benzoic acid

4-({3-[2-(3-amino-propylamino)-ethylamino]-propylamino}-methyl)-benzoic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol at 20℃;96%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

3-methoxy-2-hydroxybenzaldehyde
148-53-8

3-methoxy-2-hydroxybenzaldehyde

2-(2'-hydroxy-3'-methoxyphenyl)-1,3-bis[4-aza-5-(2''-hydroxy-3''-methoxyphenyl)but-4'-en-1'-yl]-1,3-imidazolidine

2-(2'-hydroxy-3'-methoxyphenyl)-1,3-bis[4-aza-5-(2''-hydroxy-3''-methoxyphenyl)but-4'-en-1'-yl]-1,3-imidazolidine

Conditions
ConditionsYield
In ethanol for 3h; Heating;95%
Glyoxal
131543-46-9

Glyoxal

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

trans-dodecahydro-4,5,8a,10a-tetraazaphenanthrene

trans-dodecahydro-4,5,8a,10a-tetraazaphenanthrene

Conditions
ConditionsYield
With acetic acid In ethanol; acetonitrile at 0 - 5℃; for 2h; Condensation;95%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

cyclohexane-1,2-dione
765-87-7

cyclohexane-1,2-dione

C14H26N4
245650-33-3

C14H26N4

Conditions
ConditionsYield
With acetic acid In ethanol; acetonitrile at 0 - 5℃; for 2h; Condensation;95%
In ethanol at 0℃; for 3h;80%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

fac-[(NH2(CH2)3NH(CH2)2NH(CH2)3NH2)Mo(CO)3]

fac-[(NH2(CH2)3NH(CH2)2NH(CH2)3NH2)Mo(CO)3]

Conditions
ConditionsYield
In dibutyl ether N2-atmosphere; slight excess metal carbonyl, refluxing for 2 h (returning sublimed hexacarbonyl into reaction vessel); cooling to room temp., collection of ppt., washing (hexane), drying (vac., 50°C); elem. anal.;95%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

C20H35ClN6O

C20H35ClN6O

C88H158N28O4

C88H158N28O4

Conditions
ConditionsYield
With sodium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene at 165℃; for 8h; Temperature; Solvent; Autoclave;94.64%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

terephthalaldehyde,
623-27-8

terephthalaldehyde,

C32H48N8
124481-61-4

C32H48N8

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 18h;94%
(3E)-3-[(phenylamino)methylidene]-3,4-dihydro-2H-1-benzopyran-2,4-dione
71591-96-3

(3E)-3-[(phenylamino)methylidene]-3,4-dihydro-2H-1-benzopyran-2,4-dione

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

N,N'-Bis-<(2,4-dioxochroman-3-yliden)-methylen>-1,10-diamino-4,7-diaza-decan
100200-23-5

N,N'-Bis-<(2,4-dioxochroman-3-yliden)-methylen>-1,10-diamino-4,7-diaza-decan

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃; for 0.666667h;93%
N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N,N',N'',N'''-tetratosyl-1,10-diamino-4,7-diazadecane
74676-47-4

N,N',N'',N'''-tetratosyl-1,10-diamino-4,7-diazadecane

Conditions
ConditionsYield
With sodium hydroxide In water 1.) 1 hr., 5 deg C, 2.) r.t., 3 hrs.;91%
With sodium hydroxide In diethyl ether; water at 0 - 20℃;80%
With sodium hydroxide In tetrahydrofuran for 2h; Ambient temperature;75%
With potassium carbonate at 80℃;74%
With sodium hydroxide In tetrahydrofuran at 60℃; for 4h;70%
Glyoxal
131543-46-9

Glyoxal

N,N'-bis(3-aminopropyl)-1,2-diamine
10563-26-5

N,N'-bis(3-aminopropyl)-1,2-diamine

Conditions
ConditionsYield
In ethanol Condensation; Heating;90%
In water for 72h; Ambient temperature;24%
Conditions
ConditionsYield
With triethylamine In dichloromethane for 1h; Ambient temperature; -30 deg C up to r.t.;90%

10563-26-5Relevant articles and documents

Brubaker,Schaefer

, p. 968,969 (1971)

Near-infrared photoswitching of cyclodextrin-guest complexes using lanthanide-doped LiYF4 upconversion nanoparticles

M?ller, Nadja,Hellwig, Tim,Stricker, Lucas,Engel, Sabrina,Fallnich, Carsten,Ravoo, Bart Jan

, p. 240 - 243 (2017)

This communication reports a new type of supramolecular cyclodextrin-guest complexes using cyclodextrin coated upconversion nanoparticles as hosts and monovalent and divalent azobenzenes and arylazopyrazoles as guests. A potentially biocompatible photocontrol of the interaction by isomerization of the azobenzene or arylazopyrazole was achieved by laser irradiation at 980 nm and a very low light intensity of 0.22 W cm-2

BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS

-

Paragraph 0139; 0140, (2017/09/08)

Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1-C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

Phenylglyoxal for polyamines modification and cyclam synthesis

Tripier, Rapha?l,Chuburu, Fran?oise,Le Baccon, Michel,Handel, Henri

, p. 4573 - 4579 (2007/10/03)

The bis-aminals obtained by tetraamine and phenylglyoxal condensation display various behaviours such as equilibrium between different configurations, rearrangements that lead to lactam derivatives, or amine deprotection. Our investigations about them were focused on three different linear amines, and then extended to polyazacycloalkanes cyclen and cyclam. Cyclam was also synthesised with the bis-aminals issued from condensation of linear polyamines with phenylglyoxal. The lactam derivatives described here were moreover, employed for the mono-N-functionalisation of tetraamines by phenyl-acetic acid group.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 10563-26-5