105633-68-9

Basic information

• Product Name: Silane, tris(1-methylethyl)phenoxy-
• CAS NO: 105633-68-9
• Molecular Formula: C15H26OSi
• Molecular Weight: 250.456
• Mol File: 105633-68-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, tris(1-methylethyl)phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, tris(1-methylethyl)phenoxy-(105633-68-9)
• EPA Substance Registry System: Silane, tris(1-methylethyl)phenoxy-(105633-68-9)

Safety Data

• Hazardous Substances Data: 105633-68-9(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 139-02-6 sodium phenoxide 
• 6485-79-6 chlorotriisopropylsilane 
• 721-04-0 2-phenoxy-1-phenylethanone 
• 70110-65-5 2-phenoxy-1-phenylpropane-1, 3-diol 
• 108-95-2 phenol 
• 114566-88-0 1-triisopropylsilanyl-1H-imidazole 

Downstream Products

• 767-00-0 4-cyanophenol 

Relevant articles and documents

Efficient and selective protection of alcohols and phenols with triisopropylsilyl chloride/imidazole using microwave irradiation

A very simple and efficient method is described for silylation of alcohols and phenols using triisopropylsilyl chloride and imidazole under microwave irradiation. High selectivity was observed for silylation of primary and secondary alcohols and also for structurally different phenols. (C) 2000 Published by Elsevier Science Ltd.

Ligand-Promoted Non-Directed C?H Cyanation of Arenes

This article reports the first example of a 2-pyridone accelerated non-directed C?H cyanation with an arene as the limiting reagent. This protocol is compatible with a broad scope of arenes, including advanced intermediates, drug molecules, and natural products. A kinetic isotope experiment (kH/kD=4.40) indicates that the C?H bond cleavage is the rate-limiting step. Also, the reaction is readily scalable, further showcasing the synthetic utility of this method.

Direct C-H Cyanation of Arenes via Organic Photoredox Catalysis

Methods for the direct C-H functionalization of aromatic compounds are in demand for a variety of applications, including the synthesis of agrochemicals, pharmaceuticals, and materials. Herein, we disclose the construction of aromatic nitriles via direct C-H functionalization using an acridinium photoredox catalyst and trimethylsilyl cyanide under an aerobic atmosphere. The reaction proceeds at room temperature under mild conditions and has proven to be compatible with a variety of electron-donating and -withdrawing groups, halogens, and nitrogen- and oxygen-containing heterocycles, as well as aromatic-containing pharmaceutical agents.