105669-73-6

Basic information

• Product Name: Cyclohexane, 1,1-dibromo-4-(1,1-dimethylethyl)-
• CAS NO: 105669-73-6
• Molecular Formula: C10H18Br2
• Molecular Weight: 298.061
• Mol File: 105669-73-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1,1-dibromo-4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1,1-dibromo-4-(1,1-dimethylethyl)-(105669-73-6)
• EPA Substance Registry System: Cyclohexane, 1,1-dibromo-4-(1,1-dimethylethyl)-(105669-73-6)

Safety Data

• Hazardous Substances Data: 105669-73-6(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 944-19-4 4-tert-butyl-1,1-dimethoxy-cyclohexane 
• 105732-46-5 C₁₆H₂₂O₂ 

Downstream Products

• 23525-05-5 1-bromo-4-(tert-butyl)cyclohex-1-ene 

Relevant articles and documents

Halogenative Deoxygenation of Ketones; Vinyl Bromides and/or gem-Dibromides by Cleavage of 1,3-Benzodioxoles (Ketone Phenylene Acetals) with Boron Tribromide

Representative ketones 1 have been converted in generally good yields to the respective 1,3-benzodioxoles 5 by trans-acetalization of ketone dimethyl acetals with 1,2-dihydroxybenzene, and cleaved with boron tribromide. 1,3-Benzodioxoles derived from α-unbranched aliphatic ketones gave in general a mixture of vinyl bromides and gem-dibromides; pure gem-dibromides could be selectively obtained in most of cases using a suitable reaction time. 1,3-Benzodioxoles derived from α-branched ketones gave complex mixtures and their cleavage appears to be of little synthetic signifance. 1,3-Benzodioxoles of aromatic ketones gave vinyl bromides only.Aliphatic cyclic gem-dibromides 3 were converted to the respective vinyl bromides 2 by phase-transfer-catalysed dehydrobromination.