105694-91-5Relevant articles and documents
Reduction of Vinyloxiranes with Samarium Diiodide. An Efficient Route to Functionalized Chiral, Nonracemic (E)-Allylic
Molander, Gary A.,La Belle, Bruce E.,Hahn, Gregory
, p. 5259 - 5264 (2007/10/02)
Functionalized vinyloxiranes have been found to undergo facile reductice epoxide ring opening with samarium diiodide (SmI2) in THF in the presence of a proton source to privide (E)-allylic alcohols.Reactions are exceedingly rapid, taking place ii most cas