105752-89-4Relevant articles and documents
SOME PROPERTIES OF FLUORINE-CONTAINING α,β-UNSATURATED SULFONES
Fokin, A. V.,Kolomiets, A. F.,Shkurak, S. N.,Kondrashov, N. V.,Mukhametshin, F. M.
, p. 235 - 240 (2007/10/02)
2-Chloropolyfluoroalkyl vinyl sulfones react readily with CH acids with triethylamine as catalyst, alkylate PH acids in the absence of catalyst, and form -cycloadducts with diazomethane and trimethylsilyl azide under mild conditions.In the Diels-Alder reaction fluorine-containing α,β-unsaturated sulfones react more readily than the corresponding sulfoxides and sulfides.The introduction of a CF3 group at the geminal position to the sulfonyl group increases the capacity of the compounds for -cycloaddition.
