105762-50-3

Basic information

• Product Name: Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-
• CAS NO: 105762-50-3
• Molecular Formula: C18H22OSi
• Molecular Weight: 282.458
• Mol File: 105762-50-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-(105762-50-3)
• EPA Substance Registry System: Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-(105762-50-3)

Safety Data

• Hazardous Substances Data: 105762-50-3(Hazardous Substances Data)

Upstream product

• 66132-89-6 trimethyl<2-(phenylthio)-3-phenylpropanoyl>silane 
• 591-51-5 phenyllithium 
• 105762-74-1 1,3-Diphenyl-2-phenylsulfanyl-1-trimethylsilanyl-propan-1-ol 
• 13735-81-4 1-styrenyloxytrimethylsilane 

Relevant articles and documents

Gold-catalyzed alkylation of silyl enol ethers with ortho-alkynylbenzoic acid esters

Unprecedented alkylation of silyl enol ethers has been developed by the use of ortho-alkynylbenzoic acid alkyl esters as alkylating agents in the presence of a gold catalyst. The reaction probably proceeds through the gold-induced in situ construction of leaving groups and subsequent nucleophilic attack on the silyl enol ethers. The generated leaving compound abstracts a proton to regenerate the silyl enol ether structure.

Silyl Ketone Chemistry. Synthesis of Regio- and Stereoisomerically Pure Enol Silyl Ethers Using α-Phenylthio Silyl Ketones

The addition of a number of organometallic reagents to α-phenylthio silyl ketones proceeds with good to excellent diastereoselectivity.The products undergo Brook rearrangement and fragmentation to enol silyl ethers with, in most cases, excellent stereoche