105762-51-4Relevant articles and documents
Silyl Ketone Chemistry. Synthesis of Regio- and Stereoisomerically Pure Enol Silyl Ethers Using α-Phenylthio Silyl Ketones
Reich, Hans J.,Holtan, Ronald C.,Borkowsky, Samuel L.
, p. 312 - 314 (2007/10/02)
The addition of a number of organometallic reagents to α-phenylthio silyl ketones proceeds with good to excellent diastereoselectivity.The products undergo Brook rearrangement and fragmentation to enol silyl ethers with, in most cases, excellent stereoche