1057669-39-2

Basic information

• Product Name: ethyl 5-amino-2-(cyanosulfanyl)benzoate
• Synonyms: ethyl 5-amino-2-(cyanosulfanyl)benzoate
• CAS NO: 1057669-39-2
• Molecular Formula: C10H10N2O2S
• Molecular Weight: 222.2636
• Mol File: 1057669-39-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ethyl 5-amino-2-(cyanosulfanyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5-amino-2-(cyanosulfanyl)benzoate(1057669-39-2)
• EPA Substance Registry System: ethyl 5-amino-2-(cyanosulfanyl)benzoate(1057669-39-2)

Safety Data

• Hazardous Substances Data: 1057669-39-2(Hazardous Substances Data)

Upstream product

• 582-33-2 3-aminobenzoic acid ethyl ester 
• 333-20-0 potassium thioacyanate 

Relevant articles and documents

Copper-Catalyzed Aerobic Oxidative Regioselective Thiocyanation of Aromatics and Heteroaromatics

A copper-catalyzed aerobic oxidative reaction between aromatics or heteroaromatics with KSCN is developed by using O2 as the oxidant. The combination of Cu(OTf)2, N,N,N′,N′-tetramethylethylenediamine (TMEDA) and BF3·Et2O provides an efficient catalytic system, affording substituted thiocyanation products and 2-aminobenzothiazoles in excellent yields. The reaction also possesses a good functional group tolerance for both strong electron-withdrawing and electron-donating groups.