10577-44-3

Basic information

• Product Name: Benzene, 1-methoxy-2-(1-propenyl)-
• CAS NO: 10577-44-3
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 10577-44-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-2-(1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-2-(1-propenyl)-(10577-44-3)
• EPA Substance Registry System: Benzene, 1-methoxy-2-(1-propenyl)-(10577-44-3)

Safety Data

• Hazardous Substances Data: 10577-44-3(Hazardous Substances Data)

Upstream product

• 123-62-6 propionic acid anhydride 
• 135-02-4 ortho-anisaldehyde 
• 1745-81-9 o-Allylphenol 
• 31456-98-1 methyl 3-allyl-salicylate 
• 3066-75-9 allyl diethyl phosphate 
• 578-57-4 2-bromoanisole 
• 18146-00-4 allyloxytrimethylsilane 
• 4873-09-0 allyl tosylate 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 3698-28-0 2-allylanisole 
• 60604-09-3 3-phenylpropane-3,3-d₂ 
• 1530-32-1 ethyltriphenylphosphonium bromide 

Downstream Products

• 6306-34-9 1-(2-methoxyphenyl)-2-nitropropene 
• 579-75-9 2-Methoxybenzoic acid 
• 5561-92-2 1-(2-methoxyphenyl)propan-1-one 
• 5211-62-1 1-(2-methoxyphenyl)propan-2-one 
• 93-30-1 methoxyphenamine 
• 2077-36-3 (E)-1-(2-methoxyphenyl)prop-1-ene 
• 93108-08-8 methyl 4-(2'-methoxyphenyl)butanoate 

Relevant articles and documents

Facile Synthesis of Chiral Arylamines, Alkylamines and Amides by Enantioselective NiH-Catalyzed Hydroamination

Regio- and enantioselective hydroarylamination, hydroalkylamination and hydroamidation of styrenes have been developed by NiH catalysis with a simple bioxazoline ligand under mild conditions. A wide range of enantioenriched benzylic arylamines, alkylamines and amides can be easily accessed by nitroarenes, hydroxylamines and dioxazolones, respectively as amination reagents. The chiral induction in these reactions is proposed to proceed through an enantiodifferentiating syn-hydronickellation step.

Preferential Photoreaction in a Porous Crystal, Metal-Macrocycle Framework: PdII-Mediated Olefin Migration over [2+2] Cycloaddition

A nanosized confined space with well-defined functional surfaces has great potential to control the efficiency and selectivity of catalytic reactions. Herein we report that a 1,6-diene, which normally forms an intramolecular [2+2] cycloadduct under photoirradiation, preferentially undergoes a photoinduced olefin migration in a porous crystal, metal-macrocycle framework (MMF), and alternatively [2+2] cycloaddition is completely inhibited in the confined space. A plausible reaction mechanism for olefin migration triggered by the photoinduced dissociation of the Pd-Cl bond is suggested based on UV-vis diffuse reflectance spectroscopy, single-crystal XRD, and MS-CASPT2 calculation. The substrate scope of the photoinduced olefin migration in MMF was also examined using substituted allylbenzene derivatives.

Practical iron-catalyzed allylations of aryl grignard reagents

An operationally simple iron-catalyzed reductive cross-coupling reaction between aryl halides and allyl electrophiles has been developed. The underlying domino process exhibits high versatility with respect to the allylic leaving group (acetate, tosylate, diethyl phosphate, methyl carbonate, trimethylsilanolate, methanethiolate, chloride, bromide) and high economic and environmental sustainability with respect to the catalyst system (0.2-5 mol% tris(acetylacetonato)iron(III), ligand-free) and reaction conditions (tetrahydrofuran, 0°C, 45 min).