10591-92-1

Basic information

• Product Name: Ethanone, 1-phenyl-2-(1-piperidinyl)-, oxime, (E)-
• CAS NO: 10591-92-1
• Molecular Formula: C13H18N2O
• Molecular Weight: 218.299
• Mol File: 10591-92-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-phenyl-2-(1-piperidinyl)-, oxime, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-phenyl-2-(1-piperidinyl)-, oxime, (E)-(10591-92-1)
• EPA Substance Registry System: Ethanone, 1-phenyl-2-(1-piperidinyl)-, oxime, (E)-(10591-92-1)

Safety Data

• Hazardous Substances Data: 10591-92-1(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 100-75-4 N-nitrosopiperidine 
• 110-89-4 piperidine 
• 17082-13-2 α-bromoacetophenone oxime 
• 40814-66-2 (Z)-2-chloro-1-phenylethan-1-one oxime 
• 4641-62-7 1-phenyl-2-piperidino-ethanone; hydrochloride 

Downstream Products

• 42564-23-8 2-Phenyl-6,7,8,8a-tetrahydro-3H,5H-imidazo<1,2-a>pyridin-1-oxid 
• 16451-61-9 (E)-1-Phenyl-2-(2-methylpiperidino)-ethanonoxim 
• 139881-97-3 8a-Methyl-2-phenyl-3,5,6,7,8,8a-hexahydro-imidazo<1,2-a>pyridin-1-oxid 
• 139881-91-7 (E)-2-(2-Methylpiperidino)-1-phenyl-O-(phenylcarbamoyl)-ethanonoxim 
• 139881-92-8 (E)-1-Phenyl-O-(phenylcarbamoyl)-2-(2-phenylpiperidino)-ethanonoxim 
• 139881-90-6 (E)-α-(2-phenylpiperidin-1-yl)acetophenone oxime 
• 41208-22-4 1-(2-Amino-2-phenyl-ethyl)piperidin 

Relevant articles and documents

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Nucleophilic Substitution Reactions of Phenacyl Bromide Oxime: Effect of the Solvent and the Basicity of the Nucleophile

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STEREOCHEMISTRY OF α-AMINOACETOPHENONE OXIMES STUDY OF SOLVENT EFFECTS

The aminolysis of Z-α-halogenoacetophenone oximes results in different mixtures of E- and Z-α-aminoacetophenone oximes depending on the solvent used.Assignment of configuration can be achieved by 13C NMR spectroscopy even if only one isomer is available using a strong solvent dependence of the methylene chemical shift in the case of the Z-isomers.This effect is due to the presence of different conformations in the solvents chloroform and dimethyl sulfoxide.Together with a study by vapor pressure osmometry the results provide an unambiguous proof of intramolecular hydrogen bonding of Z-α-aminoacetophenone oximes in chloroform.