105966-41-4

Basic information

• Product Name: Silane, (1,1-dimethylethyl)diphenyl(2-phenylethoxy)-
• CAS NO: 105966-41-4
• Molecular Formula: C24H28OSi
• Molecular Weight: 360.571
• Mol File: 105966-41-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)diphenyl(2-phenylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)diphenyl(2-phenylethoxy)-(105966-41-4)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)diphenyl(2-phenylethoxy)-(105966-41-4)

Safety Data

• Hazardous Substances Data: 105966-41-4(Hazardous Substances Data)

Upstream product

• 60-12-8 2-phenylethanol 
• 33729-92-9 tert-butyldiphenylsilane 

Downstream Products

• 103-45-7 acetic acid phenethyl ester 
• 94-47-3 2-Phenylethyl benzoate 
• 103-63-9 1-phenyl-2-bromoethane 
• 76358-47-9 tert-butyl(methoxy)diphenylsilane 

Relevant articles and documents

N-heterocyclic carbene organocatalysts for dehydrogenative coupling of silanes and hydroxyl compounds

Go organic! N-Heterocyclic carbene (NHC) 1,3-diisopropyl-4,5- dimethylimidazol-2-ylidene (IiPr) has been found to be an efficient and selective catalyst for the dehydrogenative coupling of a wide range of silanes and hydroxyl groups to form Si-O bonds under mild and solvent-free conditions (see scheme). Mechanistic studies indicated that the activation of hydroxyl groups by the NHC is the most plausible initial step for the process. Copyright

Versatile dehydrogenative alcohol silylation catalyzed by Cu(I)-phosphine complex

(Chemical Equation Presented) Cu(I) complexes of xanthane-based diphosphines were versatile catalysts for dehydrogenative alcohol silylation, exhibiting high activity and broad substrate scope. Highly selective silylation of 1-decanol over 2-decanol is possible even with a silylating reagent of small steric demand such as HSiMe2Ph or HSiEt3.