107369-63-1Relevant articles and documents
Reactions of 1-(2-alkoxyphenyl)alkaniminyl radicals
Leardini, Rino,McNab, Hamish,Minozzi, Matteo,Nanni, Daniele,Reed, David,Wright, Andrew G.
, p. 2704 - 2710 (2001)
Reactions of 1-(2-alkoxyphenyl)alkaniminyl radicals were studied. Generation of the iminyls 1d and 1e by standard methods in the gas-phase by flash vacuum pyrolysis (FVP) gives rise to 1,3-benzoxazines 18 and 22 by a mechanism which probably involves a 1,6-hydrogen atom translocation. The results showed that the dealkylation is an integral part of the reaction mechanism and not a subsequent reaction of 2-alkoxybenzonitriles.