1076-26-2Relevant articles and documents
Irradiation of 1-piperidinomethyl-naphthol-(2) in tetrahydrofuran. 2. Photochemistry of 2-aminomethyl-phenol
Roth,Michel
, (1971)
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Cornforth,Cornforth,Robinson
, (1943)
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Kornblum et al.
, p. 1148,1153 (1963)
Stereoselective synthesis of disubstituted naphthalene-1,2- oxides
Tius,Reddy
, p. 859 - 869 (1994)
Spiroepoxy naphthalenones, obtained from the stereoselective oxidation of 2-hydroxyalkyl-1-naphthols with sodium periodate, were converted to naphthalene-1,2-oxides by reaction with methyllithium followed by Payne rearrangement.
Organocatalytic Asymmetric Dearomatization Reaction for the Synthesis of Axial Chiral Allene-Derived Naphthalenones Bearing Quaternary Stereocenters
Woldegiorgis, Alemayehu Gashaw,Han, Zhao,Lin, Xufeng
, p. 6606 - 6611 (2021)
The highly regio-, diastereo-, and enantioselective dearomatization reaction of 1-substituted 2-naphthols and β,γ-alkynyl-α-imino esters with complete atom economy is disclosed via chiral phosphoric acid catalysis. This protocol provides facile and effici
Oxidation of 2-substituted cycloalkanones with cerium(IV) sulfate tetrahydrate in alcohols and acetic acid
He, Liangyou,Horiuchi, C. Akira
, p. 2515 - 2521 (1999)
The reaction of 2-substituted cycloalkanones with cerium(IV) sulfate tetrahydrate (CS) in alcohols and acetic acid gave the corresponding alkyl esters of oxo acids (80-96%) and oxo acids (78-96%), respectively, by oxidative cleavage of the C(R).C=O bond. In the case of 2-iodocycloalkanones in methanol, the dimethyl ester was obtained in good yield. A treatment of 5α-cholestan-3-one with CS in methanol produced 2-acetal 3-ester of 2,3-seco derivative in good yield. The effects of cerium(IV) and copper(II) salts are also discussed.
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Hill,Short,Higginbottom
, (1938)
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Smith,Horner
, p. 676,678 (1938)
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Site-selective Oxidative Dearomatization of Phenols and Naphthols into ortho-Quinols or Epoxy ortho-Quinols using Oxone as the Source of Dimethyldioxirane
Cabrera-Afonso, María J.,Carre?o, M. Carmen,Urbano, Antonio
supporting information, (2019/08/21)
A novel reactivity of dimethyldioxirane, generated in situ from Oxone and acetone, with substituted phenols and naphthols is reported. This methodology allowed the synthesis of ortho-quinols or epoxy ortho-quinols from a site-selective oxidative dearomatization process, with good yields under very mild conditions. A short total synthesis of natural product lacinilene C methyl ether is also described using this process as the key step. (Figure presented.).
NAPHTHALENE-CONTAINING POLYMERS AND METHODS OF MAKING THE SAME
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Paragraph 0021; 0081-0082, (2018/08/09)
The present disclosure relates to a dimer that includes a first hydroxyl-functionalized naphthalene group and a second hydroxyl-functionalized naphthalene group, where the first hydroxyl-functionalized naphthalene group and the second hydroxyl-functionalized naphthalene group are connected by a bridging group. The present disclosure also relates to a polymer synthesized using the dimer, as well as methods for synthesizing both the dimer and the polymer.
