1078739-22-6Relevant articles and documents
Rhodium-Catalyzed Denitrogenative Transannulation of N-Sulfonyl-1,2,3-triazoles with Glycals Giving Pyrroline-Fused N-Glycosides
Bi, Jingjing,Tan, Qiang,Wu, Hao,Liu, Qingfeng,Zhang, Guisheng
, p. 6357 - 6361 (2021)
Described here is a selective synthesis of 2,3-dihydropyrrole-fused N-glycosides through rhodium-catalyzed denitrogenative transannulation of N-sulfonyl-1,2,3-triazoles with glycals. A series of pyrroline-fused N-glycosides are afforded in moderate to exc
Copper(I)-N-Heterocyclic Carbene Complexes as Efficient Catalysts for the Synthesis of 1,4-Disubstituted 1,2,3-Sulfonyltriazoles in Air
Lazreg, Fa?ma,Cazin, Catherine S. J.
, p. 679 - 683 (2018)
Bis-NHC and mixed NHC/PR3 copper(I) complexes (NHC = N-heterocyclic carbene) were found to be efficient catalysts enabling the azide-alkyne cycloaddition reaction leading to the formation of 1,2,3-sulfonyltriazoles under Click conditions. The mechanism of this transformation was probed and decoordination of the NHC ligand (even in the NHC/PR3 mixed ligand systems) during the catalytic transformation was observed.
Method for preparing triazole derivatives
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Paragraph 0094-0097, (2019/04/06)
The invention discloses a method for preparing triazole derivatives. The method comprises the following steps: taking aryl sulfonyl azide derivatives and acetylenic derivatives as raw materials, taking cuprous iodide and ortho-aminophenol as catalysts, an