1079963-35-1

Basic information

• Product Name: propargyl 2,3,6-tri-O-benzyl-α-D-glucopyranoside
• Synonyms: propargyl 2,3,6-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 1079963-35-1
• Molecular Weight: 488.58
• Mol File: 1079963-35-1.mol

Chemical Properties

• CAS DataBase Reference: propargyl 2,3,6-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: propargyl 2,3,6-tri-O-benzyl-α-D-glucopyranoside(1079963-35-1)
• EPA Substance Registry System: propargyl 2,3,6-tri-O-benzyl-α-D-glucopyranoside(1079963-35-1)

Safety Data

• Hazardous Substances Data: 1079963-35-1(Hazardous Substances Data)

Upstream product

• 482582-68-3 2,3-di-O-benzyl-4,6-benzylidene-1-O-propynyl-α-D-glucopyranoside 
• 1253191-75-1 propargyl 2,3,4-tri-O-benzoyl α-D-mannopyranoside 
• 151168-60-4 prop-2-ynyl-α-D-glucopyranoside 
• 943859-72-1 2,3,4,6-tetra-O-acetyl-1-(2′-propargyl)-α-D-glucose 

Downstream Products

• 1079963-58-8 C₆₄H₅₈O₁₅ 
• 1079963-67-9 C₆₄H₅₈O₁₅ 
• 1198084-02-4 C₉₁H₈₀O₂₃ 
• 1198084-00-2 C₆₄H₅₈O₁₅ 
• 1357272-18-4 C₅₆H₆₆O₂₃ 

Relevant articles and documents

Click chemistry: An efficient synthesis of heterocycles substituted with steroids, saponins, and digitalis analogues

The copper-catalyzed azide-alkyne cycloaddition (CuAAC) has been used for the construction of 1,2,3-triazole containing steroids in good to excellent yields. Combination of propargylic glycosides and steroidal azides as reaction partner allowed the synthesis of a privileged class of natural product analogues. The versatility of this protocol makes this chemistry a useful attractive approach for the synthesis of target molecules. Georg Thieme Verlag Stuttgart · New York.

Gold-catalyzed glycosidations: Unusual cleavage of the interglycosidic bond while studying the armed/disarmed effect of propargyl glycosides

Armed/disarmed effect of propargyl glycosides in the presence of AuBr 3 is studied. Observed that oxophilic AuBr3 cleaves interglycosidic bond of an armed disaccharide resulting in the formation of a disaccharide and a 1,6-anhydro sugar. Trisaccharides were obtained after fine tuning the reactivity of the glycosyl donor with different protecting groups.

Gold mediated glycosylations: Selective activation of propargyl 1,2-orthoesters in the presence of aglycones containing a propargyl moiety

Selective activation of propargyl 1,2-orthoesters in the presence of propargyl glycosides and propargyl ethers was studied; a catalytic amount of AuBr3 activated the propargyloxy group of the 1,2-orthoester thereby giving access to disaccharide