109210-19-7Relevant articles and documents
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Guss,Williams
, p. 1809 (1951)
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General and practical one-pot synthesis of dihydrobenzosiloles from styrenes
Kuznetsov, Alexey,Gevorgyan, Vladimir
supporting information; experimental part, p. 914 - 917 (2012/05/05)
A one-pot synthesis of dihydrobenzosiloles from styrenes has been developed. The reaction involves the nickel-catalyzed hydrosilylation of styrene with diphenylsilane, followed by the iridium-catalyzed dehydrogenative cyclization. This method is efficient for both electron-rich and -deficient styrenes and exhibits good functional group tolerance, as well as excellent regioselectivity. The forming dihydrobenzosiloles can be efficiently converted into valuable benzosiloles or 2-hydroxyphenethyl alcohols.