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110-74-7

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110-74-7 Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 110-74-7 differently. You can refer to the following data:
1. CLEAR COLORLESS LIQUID
2. Propyl formate has a characteristic fruity (rum–plum) odor and a corresponding bittersweet flavor.

Occurrence

Reported found in plum, brandy, apple, black currant, and pineapple.

Uses

Different sources of media describe the Uses of 110-74-7 differently. You can refer to the following data:
1. Propyl formate was used in the synthesis of the radicals - CH3CH2CHOCHO, CH3CHCH2OCHO, and CH2CH2CH2OCHO by TiCl3.H2O2 radical-generating method.
2. Flavoring.

Preparation

By action of sulfuric acid on a mixture of propyl alcohol, formic acid and sodium formate; also by distilling propyl alcohol with anhydrous formic acid in the presence of sodium formate.

Taste threshold values

Taste characteristics at 50 ppm: fruity, green and ethereal with a berry lift.

General Description

A clear colorless liquid with a pleasant odor. Flash point 27°F. Slightly soluble in water and less dense than water. Hence floats on water. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

PROPYL FORMATES are esters. React with acids to liberate heat along with propanols and formic acid. Strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.

Hazard

Flammable, dangerous fire risk.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Moderately toxic by ingestion. An irritant to skin, eyes, and mucous membranes. Narcotic in high concentration. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Ignites on contact with potassium-tert-butoxide. Explosive in the form of vapor when exposed to heat or flame. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Distil the formate, then wash it with saturated aqueous NaCl, and with saturated aqueous NaHCO3 in the presence of solid NaCl, dry it with MgSO4 and fractionally distil it. [Beilstein 2 IV 26.]

Check Digit Verification of cas no

The CAS Registry Mumber 110-74-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 0 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 110-74:
(5*1)+(4*1)+(3*0)+(2*7)+(1*4)=27
27 % 10 = 7
So 110-74-7 is a valid CAS Registry Number.
InChI:InChI=1/C4H8O2/c1-2-3-6-4-5/h4H,2-3H2,1H3

110-74-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail
  • Alfa Aesar

  • (A18090)  n-Propyl formate, 97%   

  • 110-74-7

  • 100ml

  • 267.0CNY

  • Detail
  • Alfa Aesar

  • (A18090)  n-Propyl formate, 97%   

  • 110-74-7

  • 500ml

  • 1087.0CNY

  • Detail

110-74-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name PROPYL FORMATE

1.2 Other means of identification

Product number -
Other names Formic Acid Propyl Ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-74-7 SDS

110-74-7Synthetic route

butyraldehyde
123-72-8

butyraldehyde

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With oxygen; toluene-4-sulfonic acid; acetic acid at 20℃; for 2h; Baeyer-Villiger Ketone Oxidation;97%
propan-1-ol
71-23-8

propan-1-ol

sodium salt of β-mercaptonaphthalene
39689-37-7

sodium salt of β-mercaptonaphthalene

A

propyl methanoate
110-74-7

propyl methanoate

B

naphthalene-2-yl(propyl)sulfane
75052-54-9

naphthalene-2-yl(propyl)sulfane

Conditions
ConditionsYield
With carbon monoxide at 150℃; under 75006 Torr; for 10h;A n/a
B 95%
propan-1-ol
71-23-8

propan-1-ol

formic acid
64-18-6

formic acid

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With pyridine; N,N'-dibromo-N,N'-(1,2-ethanediyl)bis(p-toluenesulfonamide); triphenylphosphine In dichloromethane at 20℃;91%
With sulfuric acid In water for 4h; Reflux;75%
With sulfuric acid In 1,4-dioxane at 60℃; Equilibrium constant;
propan-1-ol
71-23-8

propan-1-ol

D-Fructose
57-48-7

D-Fructose

A

5-(n-propoxymethyl)-2-furancarboxadehyde
1917-66-4

5-(n-propoxymethyl)-2-furancarboxadehyde

B

Dipropyl ether
111-43-3

Dipropyl ether

C

propyl methanoate
110-74-7

propyl methanoate

D

n-propyl levulinate
645-67-0

n-propyl levulinate

Conditions
ConditionsYield
With poly(p-styrenesulfonic acid)-grafted carbon nanotubes at 120℃; for 24h; Sealed tube; Green chemistry; chemoselective reaction;A n/a
B n/a
C n/a
D 86%
propan-1-ol
71-23-8

propan-1-ol

dihydroxyacetone
96-26-4

dihydroxyacetone

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With Cu/Al2O3; dihydrogen peroxide In chloroform at 80℃; for 24h;83%
propan-1-ol
71-23-8

propan-1-ol

phenylacetylene
536-74-3

phenylacetylene

A

propyl methanoate
110-74-7

propyl methanoate

B

propyl benzoate
2315-68-6

propyl benzoate

Conditions
ConditionsYield
With bis-[(trifluoroacetoxy)iodo]benzene at 60℃; for 15h; Sealed tube;A n/a
B 72%
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)
121393-39-3

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

Dipropyl ether
111-43-3

Dipropyl ether

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl
342790-12-9

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

B

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With water; tetraphenylphosphonium bromide; triphenylphosphine; potassium hydroxide at 25℃; Inert atmosphere; Darkness; regioselective reaction;A 62%
B n/a
2-(tert-butylperoxy)tetrahydrofuran
31144-05-5

2-(tert-butylperoxy)tetrahydrofuran

A

4-butanolide
96-48-0

4-butanolide

B

propyl methanoate
110-74-7

propyl methanoate

C

formic acid 3-tert-butoxypropyl ester

formic acid 3-tert-butoxypropyl ester

D

acetone
67-64-1

acetone

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In various solvent(s) at 120℃; for 14h; Mechanism; Product distribution;A 30%
B 11%
C 12%
D 7%
E 61%
propan-1-ol
71-23-8

propan-1-ol

D-glucose
50-99-7

D-glucose

A

formic acid
64-18-6

formic acid

B

propyl methanoate
110-74-7

propyl methanoate

C

1-Propyl acetate
109-60-4

1-Propyl acetate

D

carbon dioxide
124-38-9

carbon dioxide

E

carbon monoxide
201230-82-2

carbon monoxide

F

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With H8[PMo7V5O40]; oxygen In water at 90℃; under 15001.5 Torr; for 24h; Autoclave;A n/a
B n/a
C n/a
D 24%
E 21%
F n/a
tripropyl orthoformate
621-76-1

tripropyl orthoformate

benzoyl chloride
98-88-4

benzoyl chloride

A

1-Chloropropane
540-54-5

1-Chloropropane

B

propyl methanoate
110-74-7

propyl methanoate

C

propyl benzoate
2315-68-6

propyl benzoate

tripropyl orthoformate
621-76-1

tripropyl orthoformate

acetaldehyde
75-07-0

acetaldehyde

A

acetaldehyde dipropyl acetal
105-82-8

acetaldehyde dipropyl acetal

B

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With sulfuric acid
1,3-dioxane
505-22-6

1,3-dioxane

A

propyl methanoate
110-74-7

propyl methanoate

B

carbon dioxide
124-38-9

carbon dioxide

C

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
In water Product distribution; Mechanism; Irradiation; γ irradiation;
1,3-dioxane
505-22-6

1,3-dioxane

A

propan-1-ol
71-23-8

propan-1-ol

B

formaldehyd
50-00-0

formaldehyd

C

1,3-dioxine
290-13-1

1,3-dioxine

D

ethene
74-85-1

ethene

E

propyl methanoate
110-74-7

propyl methanoate

F

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
Mechanism; Product distribution; Quantum yield; Heating; 185 nm vacuum-ultraviolet photolysis;
1,3-dioxane
505-22-6

1,3-dioxane

A

propyl methanoate
110-74-7

propyl methanoate

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With di-tert-butyl peroxide at 120℃; Product distribution; Rate constant; other temperature, various concentrations of peroxide, in the presence of ethyl orthoformate;
With di-tert-butyl peroxide at 120℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
dipropoxymethane
505-84-0

dipropoxymethane

tris(ethylsulfanyl)methane
6267-24-9

tris(ethylsulfanyl)methane

A

bis(ethylthio)methane
4396-19-4

bis(ethylthio)methane

B

ethyl propyl sulfide
4110-50-3

ethyl propyl sulfide

C

propyl methanoate
110-74-7

propyl methanoate

D

(ethylthio)propoxymethane

(ethylthio)propoxymethane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In various solvent(s) at 30℃; Product distribution; equilibrium concentrations; various temperature and reactant ratios, other catalysts;
dipropoxymethane
505-84-0

dipropoxymethane

A

propan-1-ol
71-23-8

propan-1-ol

B

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With ozone In tetrachloromethane at 25℃; Rate constant; k= 0.7 liter/mole.sec;
With ozone In tetrachloromethane at 18℃; Rate constant; Mechanism;
dipropoxymethane
505-84-0

dipropoxymethane

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With di-tert-butyl peroxide at 130℃; Rate constant; kinetic isotope effect; further temperatures;
tripropyl orthoformate
621-76-1

tripropyl orthoformate

A

propane
74-98-6

propane

B

propyl methanoate
110-74-7

propyl methanoate

C

Dipropyl carbonate
623-96-1

Dipropyl carbonate

D

propionaldehyde
123-38-6

propionaldehyde

Conditions
ConditionsYield
With di-tert-butyl peroxide In chlorobenzene at 140℃; for 4h; Kinetics; Mechanism; Product distribution; various temperatures, rates of formation;
carbon monoxide
201230-82-2

carbon monoxide

A

ethanol
64-17-5

ethanol

B

Methyl formate
107-31-3

Methyl formate

C

propyl methanoate
110-74-7

propyl methanoate

D

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 2-hydroxypyridin; hydrogen; acetylacetonatodicarbonylrhodium(l) In various solvent(s) at 230℃; under 1499480 Torr; for 4.5h; Further byproducts given. Title compound not separated from byproducts;A 191 mmol
B 52 mmol
C 29 mmol
D 1000 mmol
1,3-Bis(1,3-dioxan-2-yloxy)propane
81381-75-1

1,3-Bis(1,3-dioxan-2-yloxy)propane

A

trimethylene carbonate
2453-03-4

trimethylene carbonate

B

propyl methanoate
110-74-7

propyl methanoate

C

2-propoxy-1,3-dioxane
85533-20-6

2-propoxy-1,3-dioxane

D

3-([1,3]Dioxan-2-yloxy)-propionaldehyde
85533-24-0

3-([1,3]Dioxan-2-yloxy)-propionaldehyde

E

propyl 3-(1,3-dioxan-2-yloxy)propyl carbonate
85533-23-9

propyl 3-(1,3-dioxan-2-yloxy)propyl carbonate

Conditions
ConditionsYield
With di-tert-butyl peroxide at 130℃; for 0.5h; Product distribution;A 0.02 mol
B 0.01 mol
C 0.02 mol
D 0.01 mol
E 0.06 mol
2-propoxy-1,3-dioxane
85533-20-6

2-propoxy-1,3-dioxane

A

trimethylene carbonate
2453-03-4

trimethylene carbonate

B

propane
74-98-6

propane

C

propyl methanoate
110-74-7

propyl methanoate

D

Dipropyl carbonate
623-96-1

Dipropyl carbonate

E

propionaldehyde
123-38-6

propionaldehyde

Conditions
ConditionsYield
With di-tert-butyl peroxide In chlorobenzene at 130℃; Product distribution; Rate constant; Mechanism;
Formic acid 4-formyloxy-3-methyl-butyl ester

Formic acid 4-formyloxy-3-methyl-butyl ester

A

sec-butyl formate
589-40-2

sec-butyl formate

B

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With di-tert-butyl peroxide at 140℃; for 3h; conversion, concentration of products;
2-propoxyethanol
2807-30-9

2-propoxyethanol

A

2-ethyl-1,3-dioxolane
2568-96-9

2-ethyl-1,3-dioxolane

B

propyl methanoate
110-74-7

propyl methanoate

C

n-propoxyacetaldehyde
67365-39-3

n-propoxyacetaldehyde

Conditions
ConditionsYield
With hydroxide at 23.85℃; under 760 Torr; Rate constant; Product distribution; Mechanism;A 5.4 % Chromat.
B 47 % Chromat.
C 15 % Chromat.
propan-1-ol
71-23-8

propan-1-ol

sodium n-propoxide
6819-41-6

sodium n-propoxide

CO

CO

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
Geschwindigkeit der Umsetzung;
Dipropyl ether
111-43-3

Dipropyl ether

A

propyl propionate
106-36-5

propyl propionate

B

propyl methanoate
110-74-7

propyl methanoate

C

acetaldehyde
75-07-0

acetaldehyde

D

propionaldehyde
123-38-6

propionaldehyde

Conditions
ConditionsYield
With nitric oxide Kinetics; Oxidation; UV-irradiation;
propan-1-ol
71-23-8

propan-1-ol

carbon dioxide
124-38-9

carbon dioxide

A

formic acid
64-18-6

formic acid

B

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With hydrogen; triethylamine; TpRu(PPh3)(CH3CN)H at 100℃; under 38000 Torr; for 16h;
propan-1-ol
71-23-8

propan-1-ol

carbon dioxide
124-38-9

carbon dioxide

carbon monoxide
201230-82-2

carbon monoxide

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With hydrogen; potassium carbonate at 169.84℃; under 22502.3 Torr; for 2h;
propan-1-ol
71-23-8

propan-1-ol

Reaxys ID: 11463886

Reaxys ID: 11463886

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
Conversion of starting material;
tetrahydrofuran
109-99-9

tetrahydrofuran

propyl methanoate
110-74-7

propyl methanoate

Conditions
ConditionsYield
With oxygen; [Ru(CO)2Cp]2 under 375.038 Torr; for 168h;
n-Octylamine
111-86-4

n-Octylamine

propyl methanoate
110-74-7

propyl methanoate

N-octylformamide
6282-06-0

N-octylformamide

Conditions
ConditionsYield
With Cp*2Sm(THF)2 In toluene Ambient temperature; further reagent: SmI2;99%
propyl methanoate
110-74-7

propyl methanoate

dibutylamine
111-92-2

dibutylamine

N,N-dibutylformamide
761-65-9

N,N-dibutylformamide

Conditions
ConditionsYield
With Cp*2Sm(THF)2 In toluene Ambient temperature;99%
propyl methanoate
110-74-7

propyl methanoate

(S)-2-tert-butoxycarbonylamino-pentanedioic acid 1-benzyl ester 5-ethyl ester

(S)-2-tert-butoxycarbonylamino-pentanedioic acid 1-benzyl ester 5-ethyl ester

N-tert-butoxycarbonyl-2-benzyloxycarbonyl-4-ethoxycarbonyl-2,3-dihydro-1H-pyrrole

N-tert-butoxycarbonyl-2-benzyloxycarbonyl-4-ethoxycarbonyl-2,3-dihydro-1H-pyrrole

Conditions
ConditionsYield
Stage #1: (S)-2-tert-butoxycarbonylamino-pentanedioic acid 1-benzyl ester 5-ethyl ester With sodium t-butanolate In tetrahydrofuran at -70℃; for 3h; Inert atmosphere;
Stage #2: propyl methanoate In tetrahydrofuran at -70℃; for 5h;
Stage #3: With trifluoroacetic acid In dichloromethane at 5 - 25℃; for 4h;
95.7%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

propyl methanoate
110-74-7

propyl methanoate

2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

Conditions
ConditionsYield
With magnesium; lithium chloride In tetrahydrofuran; dichloromethane at 20 - 67℃; for 1.5h; Time;91.1%
propyl methanoate
110-74-7

propyl methanoate

1-(Aminomethyl)isoquinoline dihydrochloride
19382-38-8

1-(Aminomethyl)isoquinoline dihydrochloride

2-formamidomethylisoquinoline
58021-71-9

2-formamidomethylisoquinoline

Conditions
ConditionsYield
With TEA In ethanol for 2h; Heating;89%
propyl methanoate
110-74-7

propyl methanoate

p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

1-propyl 4-(trifluoromethyl)benzoate
959101-12-3

1-propyl 4-(trifluoromethyl)benzoate

Conditions
ConditionsYield
Stage #1: p-trifluoromethylphenyl bromide With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: propyl methanoate In tetrahydrofuran; hexane at -78℃; for 3h;
Stage #3: With propan-1-ol; iodine; potassium carbonate In tetrahydrofuran; hexane at -78 - 20℃; for 14h;
86%
propyl methanoate
110-74-7

propyl methanoate

2,2-diethoxy-ethanamine
645-36-3

2,2-diethoxy-ethanamine

2,2-diethoxy-1-formylaminoethane
53089-10-4

2,2-diethoxy-1-formylaminoethane

Conditions
ConditionsYield
for 3h; Reflux;86%
propyl methanoate
110-74-7

propyl methanoate

benzamide
55-21-0

benzamide

propyl benzoate
2315-68-6

propyl benzoate

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride hexahydrate In hexane; water at 80℃; for 14h;86%
Adipic acid
124-04-9

Adipic acid

propyl methanoate
110-74-7

propyl methanoate

A

Hexanedioic acid monopropyl ester
6939-72-6

Hexanedioic acid monopropyl ester

B

di-n-propyl adipate
106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With Dowex 50W-X2 (50-100 mesh) In octane at 70℃; for 2.66667h;A 85%
B 6%
With Dowex 50Wx2 In octane at 70℃; for 2.66667h; Esterification;A 85%
B 6%
propyl methanoate
110-74-7

propyl methanoate

quinolin-2-ylmethanamine bischlorohydrate
18004-62-1

quinolin-2-ylmethanamine bischlorohydrate

N-(2-Quinolylmethyl)formamide
63111-81-9

N-(2-Quinolylmethyl)formamide

Conditions
ConditionsYield
With TEA In ethanol for 2h; Heating;83%
propyl methanoate
110-74-7

propyl methanoate

benzoic acid
65-85-0

benzoic acid

propyl benzoate
2315-68-6

propyl benzoate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 130℃; for 12h; Sealed tube;82%
propyl methanoate
110-74-7

propyl methanoate

aniline
62-53-3

aniline

Formanilid
103-70-8

Formanilid

Conditions
ConditionsYield
With Cp*2Sm(THF)2 In toluene Ambient temperature;80%
propyl methanoate
110-74-7

propyl methanoate

N-cyanoacetamidine
56563-07-6

N-cyanoacetamidine

5-azacytosine
931-86-2

5-azacytosine

Conditions
ConditionsYield
at 115℃; for 2h;80%
oxalyl dichloride
79-37-8

oxalyl dichloride

propyl methanoate
110-74-7

propyl methanoate

dichloromethyl propyl ether
65611-08-7

dichloromethyl propyl ether

Conditions
ConditionsYield
With N-methyl-N-phenylformamide at 60℃; for 9h;76%
propyl methanoate
110-74-7

propyl methanoate

3-(aminomethyl)isoquinoline dihydrochloride

3-(aminomethyl)isoquinoline dihydrochloride

3-formamidomethylisoquinoline
157405-78-2

3-formamidomethylisoquinoline

Conditions
ConditionsYield
With TEA In ethanol for 2h; Heating;75%
deoxyvasicinone
530-53-0

deoxyvasicinone

propyl methanoate
110-74-7

propyl methanoate

α-hydroxymethylenedeoxyvasicin-4-one
62062-74-2

α-hydroxymethylenedeoxyvasicin-4-one

Conditions
ConditionsYield
Stage #1: deoxyvasicinone; propyl methanoate With sodium at 0 - 20℃;
Stage #2: With water Cooling with ice;
75%
propyl methanoate
110-74-7

propyl methanoate

2-(Aminomethyl)-4-methoxyquinoline dihydrochloride
76278-33-6

2-(Aminomethyl)-4-methoxyquinoline dihydrochloride

<(4-Methoxy-2-quinolyl)methyl>formamide
132833-02-4

<(4-Methoxy-2-quinolyl)methyl>formamide

Conditions
ConditionsYield
With TEA In ethanol for 2h; Heating;74%
propyl methanoate
110-74-7

propyl methanoate

dichloromethyl propyl ether
65611-08-7

dichloromethyl propyl ether

Conditions
ConditionsYield
With oxalyl dichloride; N-methyl-N-phenylformamide at 60℃; for 17h;74%
With oxalyl dichloride; N-methyl-N-phenylformamide
propyl methanoate
110-74-7

propyl methanoate

5-(4'-cyanobiphenyl-4-oxy)pentylamine

5-(4'-cyanobiphenyl-4-oxy)pentylamine

1-formamido-5-(4'-cyanobiphenyl-4-oxy)pentane

1-formamido-5-(4'-cyanobiphenyl-4-oxy)pentane

Conditions
ConditionsYield
for 24h; Inert atmosphere; Reflux;73%
styrene
292638-84-7

styrene

propyl methanoate
110-74-7

propyl methanoate

(E)-propyl cinnamate
74513-58-9

(E)-propyl cinnamate

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium dichloride; trimethylsilyl cyanide; 4-cyano-1-isopropoxypyridin-1-ium trifluoromethanesulfonate at 20℃; for 12h; Schlenk technique; Inert atmosphere; Irradiation;72%
propyl methanoate
110-74-7

propyl methanoate

N-(2-[2,2-bis(decyloxymethyl)ethoxy]carbonylethyl)amine

N-(2-[2,2-bis(decyloxymethyl)ethoxy]carbonylethyl)amine

N-formyl-[2-(2,2-bis(decyloxymethyl)ethoxy)carbonylethyl]amine

N-formyl-[2-(2,2-bis(decyloxymethyl)ethoxy)carbonylethyl]amine

Conditions
ConditionsYield
With potassium carbonate for 21h; Inert atmosphere; Reflux;68%
propyl methanoate
110-74-7

propyl methanoate

N-[2-(2,2-bis[2,2-di(decyloxymethyl)ethoxymethyl]ethoxy)carbonylethyl]amine

N-[2-(2,2-bis[2,2-di(decyloxymethyl)ethoxymethyl]ethoxy)carbonylethyl]amine

N-formyl-[2-(2,2-bis(2,2-di(decyloxymethyl)ethoxymethyl)ethoxy)carbonylethyl]amine

N-formyl-[2-(2,2-bis(2,2-di(decyloxymethyl)ethoxymethyl)ethoxy)carbonylethyl]amine

Conditions
ConditionsYield
With potassium carbonate for 41h; Inert atmosphere; Reflux;68%
propyl methanoate
110-74-7

propyl methanoate

propan-1-ol
71-23-8

propan-1-ol

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium; P(C4H9)3 In pyridine at 180℃; for 8h;67%
dimethylacetylene
503-17-3

dimethylacetylene

propyl methanoate
110-74-7

propyl methanoate

(2E,5E)-3,5-dimethylhepta-2,5-dien-4-ol
49587-60-2

(2E,5E)-3,5-dimethylhepta-2,5-dien-4-ol

Conditions
ConditionsYield
With isobutylmagnesium bromide; titanocene dichloride65%

110-74-7Relevant articles and documents

Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials

Liu, Ruliang,Chen, Jinzhu,Huang, Xing,Chen, Limin,Ma, Longlong,Li, Xinjun

, p. 2895 - 2903 (2013)

A series of sulfonic acid-functionalized carbon materials (C-SO 3H), including poly(p-styrenesulfonic acid)-grafted carbon nanotubes (CNT-PSSA), poly(p-styrenesulfonic acid)-grafted carbon nanofibers (CNF-PSSA), benzenesulfonic acid-grafted CMK-5 (CMK-5-BSA), and benzenesulfonic acid-grafted carbon nanotubes (CNT-BSA), have been studied for fructose dehydration to 5-hydroxymethylfurfural (HMF) and fructose alcoholysis to alkyl levulinate. A study for optimizing the reaction conditions such as the catalyst loading, the reaction time, and the temperature has been performed. Under the optimal conditions, high HMF and ethyl levulinate yields of up to 89% and 86%, respectively, are obtained. The catalytic activities of C-SO3H for the conversions of fructose into both HMF and ethyl levulinate follow the order of their acid strength. The relationship between the catalytic activity and acid density of C-SO3H shows a linear correspondence in the fructose dehydration to HMF. The facile separation, ease of recovery, and high thermal stability make the developed C-SO3H efficient and environment-friendly catalytic materials for transforming biomass carbohydrate into fine chemicals.

Selective aerobic oxidation of cyclic ethers to lactones over Au/CeO2 without any additives

Liu, Shulin,Li, Shaopeng,Shen, Xiaojun,Wang, Yanyan,Du, Juan,Chen, Bingfeng,Han, Buxing,Liu, Huizhen

supporting information, p. 2638 - 2641 (2020/03/10)

Selective oxidation of ethers to lactones with O2 as a benign oxidant using Au/CeO2 as the catalyst has been developed. The oxygen vacancies and Au0 species on the surface of CeO2 contribute to the activation of O2. The excellent selectivity of lactones is due to the adsorption of ethers and activation of the C(sp3)-H bond on Au/CeO2.

Method for preparing formate-type compound

-

Paragraph 0039; 0047; 0048, (2018/07/30)

The invention discloses a method for preparing a formate-type compound. The method comprises the following steps of: adopting an alcohol-type compound and 1,3-dihydroxyacetone as reaction raw materials, and under the existence of a composite catalyst and an oxidant, reacting for 2-48 hours in a reaction medium in a reactor at a reaction temperature of 25-100 DEG C so as to obtain the formate-typecompound. The method disclosed by the invention is simple, and is mild in reaction condition, and by the method, a target product can be obtained by low cost and high yield; the used catalyst has highcatalytic activity, and is easily separated from a reaction system to be repeatedly used; the whole process is environment-friendly, and the reaction raw material (1,3-dihydroxyacetone) is easily converted from a side product (glycerol) of biodiesel, so that the utilization of the glycerol is promoted.

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