111-39-7

Basic information

• Product Name: N-(N-PROPYL)ETHYLENEDIAMINE
• Synonyms: 2-PROPYLAMINOETHYLAMINE;2-(N-PROPYLAMINO)ETHYLAMINE;N-PROPYLETHYLENEDIAMINE;N-(N-PROPYL)ETHYLENEDIAMINE;Ethylenediamine, N-propyl-;N-PROPYLETHYLENEDIAMINE, 97+%;N-Propyl-1,2-ethanediamine;N-Propylethane-1,2-diamine
• CAS NO: 111-39-7
• Molecular Formula: C₅H₁₄N₂
• Molecular Weight: 102.18
• EINECS: 203-864-9
• Mol File: 111-39-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: -30.89°C (estimate)
• Boiling Point: 147-150 °C(lit.)
• Flash Point: 59 °F
• Appearance: Clear colorless/Liquid
• Density: 0.829 g/mL at 25 °C(lit.)
• Vapor Pressure: 3.39mmHg at 25°C
• Refractive Index: n20/D 1.441(lit.)
• Storage Temp.: Flammables area
• PKA: 10.26±0.19(Predicted)
• Sensitive: Air Sensitive
• BRN: 1697232
• CAS DataBase Reference: N-(N-PROPYL)ETHYLENEDIAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(N-PROPYL)ETHYLENEDIAMINE(111-39-7)
• EPA Substance Registry System: N-(N-PROPYL)ETHYLENEDIAMINE(111-39-7)

Safety Data

• Hazard Codes: Xi,C,F
• Statements: 10-37/38
• Safety Statements: 23
• RIDADR: UN 2734 8/PG 2
• WGK Germany: 3
• TSCA: T
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 111-39-7(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLORLESS LIQUID

Uses

N-Propylethylenediamine was used in the synthesis of N-acetyl-N′-propylethylenediamine.

General Description

N-Propylethylenediamine columns help in quantitatively removing Cu(2+) from buffered solutions at pH 6.

InChI:InChI=1/C5H14N2/c1-2-4-7-5-3-6/h7H,2-6H2,1H3/p+2

Upstream product

• 107-10-8 propylamine 
• 2576-47-8 2-bromoethylamine hydrobromide 
• 151-56-4 ethyleneimine 
• 71-23-8 propan-1-ol 
• 107-15-3 ethylenediamine 
• 41239-30-9 (2-Propylamino-ethyl)-phosphoramidic acid diisopropyl ester 
• 106-94-5 propyl bromide 
• 123-38-6 propionaldehyde 
• 16728-81-7 propylamino acetonitrile 
• 534-26-9 lysidine 

Downstream Products

• 22478-99-5 N,N'-Di(p-methoxybenzoyl)-N-n-propylethylendiamin 
• 1245169-76-9 2-({[2-(propylamino)ethyl]imino}methyl)phenol 
• 1601472-95-0 3-bromo-1-(3-chloropyridin-2-yl)-N-(4-cyano-2-methyl-6-((2-(propylamino)ethyl)carbamoyl)phenyl)-1H-pyrazole-5-carboxamide 
• 1601472-89-2 3-bromo-N-(4-chloro-2-methyl-6-((2-(propylamino)ethyl)carbamoyl)phenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxamide 
• 1476770-99-6 [AgCl(κ¹-S-(n-propylimidazolidine-2-thione)(triphenylphosphine)₂)] 
• 1392475-93-2 [N₁,N₂-bis(4-nitrophenyl)-N₁-propylethane-1,2-diamine] 
• 1009347-67-4 C₃₉H₄₁N₇O₂ 

Relevant articles and documents

The synthesis of asymmetric ethylenediamine derivatives catalyzed by ion-exchange resins

The ring-opening reaction of aziridine with alkylamines over a series of ion-exchange resins was investigated. Among these catalysts, D001-CC exhibited excellent catalytic performance. The catalysts were characterized by SEM and N2 adsorption-desorption. The results indicated that the selectivity of N,N-diethylethylenediamine mainly depended on the acidity and S BET of the resins. Strong Br?nsted acid sites played an important role on the conversion of aziridine, and the distribution of acid sites on catalyst had a significant effect on the selectivity of N,N-diethylethylenediamine. The reaction parameters, such as reaction time, molar ratio, reaction temperature, and catalyst loading, were also optimized and N,N-diethylethylenediamine was obtained in an excellent yield of 97 %. Furthermore, D001-CC was efficiently recycled five times by simple treatment with large amounts of deionized water and mineral acid. Finally, a series of asymmetric ethylenediamine derivatives were successfully synthesized with this method. Therefore, a simple and versatile process for the synthesis of asymmetric ethylenediamine derivatives has been established over ion-exchange resins.

N-alkylation of ethylenediamine with alcohols catalyzed by CuO-NiO/?3-Al2O3

A simple method for N-alkylation of 1,2-diaminoethane with different alcohols in a fixed-bed reactor using cheap CuO-NiO/?3-Al2O3 as the catalyst has been developed. The present catalytic system was applicable in the N-alkylation of

Pyridylcarbonyl and thiocarbonyl derivatives useful as fungicides

The substituted heteroaryl compounds of this invention are good fungicides. In particular, they possess especially good activity against Bean Powdery Mildew, and other plant fungal diseases.