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111-45-5 Usage

Chemical Properties

Colorless transparent liquid

Flammability and Explosibility

Flammable

Check Digit Verification of cas no

The CAS Registry Mumber 111-45-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 1 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 111-45:
(5*1)+(4*1)+(3*1)+(2*4)+(1*5)=25
25 % 10 = 5
So 111-45-5 is a valid CAS Registry Number.
InChI:InChI=1/C5H10O2/c1-2-4-7-5-3-6/h2,6H,1,3-5H2

111-45-5 Well-known Company Product Price

  • Brand
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  • CAS number
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  • Detail
  • Aldrich

  • (476234)  2-Allyloxyethanol  98%

  • 111-45-5

  • 476234-250ML

  • 444.60CNY

  • Detail
  • Aldrich

  • (476234)  2-Allyloxyethanol  98%

  • 111-45-5

  • 476234-1L

  • 1,241.37CNY

  • Detail

111-45-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Allyloxyethanol

1.2 Other means of identification

Product number -
Other names allylcellosolve

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111-45-5 SDS

111-45-5Synthetic route

ethylene glycol
107-21-1

ethylene glycol

allyl bromide
106-95-6

allyl bromide

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With sodium hydride In dimethyl sulfoxide for 3h;95%
With potassium hydroxide In water; dimethyl sulfoxide 1.) 0 deg C, 30 min, 2.) r.t., 5 h;86%
With sodium76%
ethylene glycol
107-21-1

ethylene glycol

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With potassium hydroxide78%
With potassium carbonate at 100℃; for 8h;60%
2-(prop-2-ynyloxy)ethanol
3973-18-0

2-(prop-2-ynyloxy)ethanol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
Stage #1: 2-(prop-2-ynyloxy)ethanol With lithium aluminium tetrahydride In 1,4-dioxane at -5℃; for 6h; Reflux;
Stage #2: With water; sodium hydroxide In 1,4-dioxane at 0℃;
78%
oxirane
75-21-8

oxirane

allyl alcohol
107-18-6

allyl alcohol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With sodium hydroxide at 120℃;
ethylene glycol
107-21-1

ethylene glycol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With sodium und anschliessenden Erhitzen mit Allylbromid auf 110grad;
2-vinyl-1,3-dioxolane
3984-22-3

2-vinyl-1,3-dioxolane

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With lithium aluminium tetrahydride; aluminium trichloride In diethyl ether
n-Pent-4-enyl alcohol
821-09-0

n-Pent-4-enyl alcohol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With pyridine; lead(IV) acetate; calcium carbonate In benzene Heating;
allyl alcohol
107-18-6

allyl alcohol

2-chloro-ethanol
107-07-3

2-chloro-ethanol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With sodium In benzene
allyl bromide
106-95-6

allyl bromide

monosodium compound of glycol

monosodium compound of glycol

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

allyl bromide
106-95-6

allyl bromide

sodium-glycolate

sodium-glycolate

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

bis(2-(2-propenyloxy)ethyl) maleate
109126-88-7

bis(2-(2-propenyloxy)ethyl) maleate

dyanol 22
901-44-0

dyanol 22

A

condensate of bis(2-allyloxyethyl) maleate with ethylene oxide 2-mol adduct of bisphenol A

condensate of bis(2-allyloxyethyl) maleate with ethylene oxide 2-mol adduct of bisphenol A

B

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With dibutyltin(IV) oxide; ester of 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid and pentaerythritol at 160℃; under 3.0003 Torr;
diallylcarbonate
15022-08-9

diallylcarbonate

ethylene glycol
107-21-1

ethylene glycol

A

[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

B

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine In tetrahydrofuran at 20 - 25℃; for 24h; Inert atmosphere;A 15 %Spectr.
B 49 %Spectr.
C16H25NO2

C16H25NO2

A

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

B

C13H20N2O

C13H20N2O

C

3-(diethylamino)benzaldehyde
116496-09-4

3-(diethylamino)benzaldehyde

D

(3-(diethylamino)phenyl)methanol
58293-93-9

(3-(diethylamino)phenyl)methanol

Conditions
ConditionsYield
With water; acetonitrile for 1.5h; UV-irradiation;A 94 %Spectr.
B n/a
C n/a
D n/a
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

2-(4-methoxybenzyloxy)-5-hydroxybenzonitrile
1434804-25-7

2-(4-methoxybenzyloxy)-5-hydroxybenzonitrile

5-(2-(allyloxy)ethoxy)-2-(4-methoxybenzyloxy)benzonitrile
1434804-31-5

5-(2-(allyloxy)ethoxy)-2-(4-methoxybenzyloxy)benzonitrile

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In dichloromethane at 20℃; Mitsunobu Displacement;100%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

t-butyl diazoacetate
35059-50-8

t-butyl diazoacetate

tert-butyl 2-(2-allyloxyethoxy)acetate

tert-butyl 2-(2-allyloxyethoxy)acetate

Conditions
ConditionsYield
With rhodium(II) acetate In dichloromethane at 25℃; for 18h; Inert atmosphere;100%
C48H56O12Si10
676229-30-4

C48H56O12Si10

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

C63H86O18Si10

C63H86O18Si10

Conditions
ConditionsYield
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane In toluene; xylene at 20℃; for 3h;99.1%
dihydrogen hexachloroplatinate In toluene at 20℃; for 3h;
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

benzoyl chloride
98-88-4

benzoyl chloride

1-allyloxy-2-benzoyloxy-ethane
70965-00-3

1-allyloxy-2-benzoyloxy-ethane

Conditions
ConditionsYield
Stage #1: ethylene glycol monoallyl ether; benzoyl chloride In dichloromethane at 20℃;
Stage #2: With poly{trans-bicyclo[2.2.1]hept-5-ene-2,3-di(chlorocarbonyl)} In dichloromethane Heating;
99%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

2-bromoisobutyric acid bromide
20769-85-1

2-bromoisobutyric acid bromide

2-(allyloxy)ethyl 2-bromo-2-methylpropanoate

2-(allyloxy)ethyl 2-bromo-2-methylpropanoate

Conditions
ConditionsYield
With pyridine In dichloromethane at -10 - 20℃; for 3.5h; Cooling with ice;99%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

diethyl (1-((4-methylphenyl)sulfonamido)prop-1-en-1-yl)phosphonate

diethyl (1-((4-methylphenyl)sulfonamido)prop-1-en-1-yl)phosphonate

C19H30NO6PS

C19H30NO6PS

Conditions
ConditionsYield
With tributylphosphine; di-isopropyl azodicarboxylate In tetrahydrofuran; toluene at 20℃; for 1h; Mitsunobu Displacement; Inert atmosphere;99%
maleic anhydride
108-31-6

maleic anhydride

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

maleic acid (2-allyloxyethyl)ester

maleic acid (2-allyloxyethyl)ester

Conditions
ConditionsYield
With dmap for 2h; Reflux;98.5%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

N,N-dimethyl-2,3,3,3-tetrafluoropropionamide
13280-34-7

N,N-dimethyl-2,3,3,3-tetrafluoropropionamide

C8H10F4O3

C8H10F4O3

Conditions
ConditionsYield
With phosphoric acid; toluene-4-sulfonic acid In 2-methyltetrahydrofuran at 75℃; for 10h; Temperature;98.1%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

D,L-4,5-Dihydro-3-isocyanato-(3H)-thiophen-2-on
38869-93-1

D,L-4,5-Dihydro-3-isocyanato-(3H)-thiophen-2-on

C10H15NO4S

C10H15NO4S

Conditions
ConditionsYield
With dibutyltin(II) dilaurate In ethyl acetate at 65℃; for 4h; Schlenk technique; Inert atmosphere;98%
phthalic anhydride
85-44-9

phthalic anhydride

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

phthalic acid mono(2-allyloxyethyl) ester

phthalic acid mono(2-allyloxyethyl) ester

Conditions
ConditionsYield
With pyridine; dmap In toluene for 3h; Reflux;98%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

mercaptopropylmethyldimethoxysilane
31001-77-1

mercaptopropylmethyldimethoxysilane

3-methoxy-3-methyl-2,11-dioxa-7-thia-3-silatridecan-13-ol

3-methoxy-3-methyl-2,11-dioxa-7-thia-3-silatridecan-13-ol

Conditions
ConditionsYield
With 2,2-dimethoxy-2-phenylacetophenone for 0.666667h; UV-irradiation;98%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

Bis(trimethylsilyl)ethyne
14630-40-1

Bis(trimethylsilyl)ethyne

2-(2-propenyloxy)ethoxytrimethylsilane
24628-30-6

2-(2-propenyloxy)ethoxytrimethylsilane

Conditions
ConditionsYield
With potassium hexamethylsilazane In neat (no solvent) at 40℃; for 0.5h; Inert atmosphere; Green chemistry;98%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-(allyloxy)ethyl 4-methylbenzenesulfonate
50563-72-9

2-(allyloxy)ethyl 4-methylbenzenesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 1h;97%
With dmap; triethylamine In dichloromethane at 0 - 20℃;95%
With dmap; triethylamine In water Inert atmosphere;93%
2,3-dichloro-5-nitropyridine
22353-40-8

2,3-dichloro-5-nitropyridine

ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

2-(2-(allyloxy)ethoxy)-3-chloro-5-nitropyridine

2-(2-(allyloxy)ethoxy)-3-chloro-5-nitropyridine

Conditions
ConditionsYield
Stage #1: ethylene glycol monoallyl ether With sodium hydride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: 2,3-dichloro-5-nitropyridine In tetrahydrofuran at -20 - 20℃; for 1h;
97%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

bis(1,4-dioxan-2-ylmethyl)selenide

bis(1,4-dioxan-2-ylmethyl)selenide

Conditions
ConditionsYield
Stage #1: ethylene glycol monoallyl ether With selenium dibromide In chloroform at -20 - 20℃; for 4h;
Stage #2: With sodium hydrogencarbonate In chloroform at 20℃; for 16h; Reagent/catalyst;
96%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

C16H36O4Si4

C16H36O4Si4

C36H76O12Si4

C36H76O12Si4

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 95℃; for 4h; Inert atmosphere; regioselective reaction;96%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

acetic anhydride
108-24-7

acetic anhydride

acetic acid 2-allyloxyethyl ester
70964-99-7

acetic acid 2-allyloxyethyl ester

Conditions
ConditionsYield
ruthenium trichloride In acetonitrile at 20℃; for 1h;95%
With sulfuric acid
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

perfluoroheptyl iodide
335-58-0

perfluoroheptyl iodide

6-(F-heptyl)-5-iodo-3-oxa-5-hexan-1-ol
25431-54-3

6-(F-heptyl)-5-iodo-3-oxa-5-hexan-1-ol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 70℃; for 22h;95%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

4-(1,4-dioxahept-6-enyl)nitrobenzene
374588-10-0

4-(1,4-dioxahept-6-enyl)nitrobenzene

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In benzene for 4h; Heating;95%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

methanesulfonic acid 2-propenyloxyethyl ester
153901-22-5

methanesulfonic acid 2-propenyloxyethyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 18h;95%
With triethylamine In tetrahydrofuran at 20℃; for 1.5h;74%
With pyridine at 0 - 20℃;71%
In dichloromethane at 0℃;
With triethylamine In dichloromethane at 0℃; for 2h;
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

boric acid
11113-50-1

boric acid

tris(2-alloxyethyl)borate
86281-85-8

tris(2-alloxyethyl)borate

Conditions
ConditionsYield
In benzene byproducts: H2O; B-compd. to alcohol molar ratio 1:4, boiling (6-14 h) to the end of water distillation off; benzene removing in vacuum; elem. anal.;94%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

1-butyl-9-hydro-1,1,3,3,5,5,7,7,9,9-decamethyl pentasiloxane
121263-53-4

1-butyl-9-hydro-1,1,3,3,5,5,7,7,9,9-decamethyl pentasiloxane

C19H50O6Si5
1052075-56-5

C19H50O6Si5

Conditions
ConditionsYield
complex of alkali-neutralized chloroplatinic acid with vinyl siloxane In toluene at 70 - 100℃;94%
With platinum(IV) chloride; platinum In toluene at 70 - 100℃; for 2h;94%
With chloroplatinic acid alkali neutralized vinylsiloxane In toluene at 70 - 100℃; for 2h;94%
With dihydrogen hexachloroplatinate In toluene at 70 - 100℃; for 2h;94%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

3-(N,N-diethylamino)benzyl chloride
63133-81-3

3-(N,N-diethylamino)benzyl chloride

C16H25NO2

C16H25NO2

Conditions
ConditionsYield
Stage #1: ethylene glycol monoallyl ether With tetrabutylammomium bromide; sodium hydride In N,N-dimethyl-formamide; mineral oil at -10 - 20℃; for 0.75h;
Stage #2: 3-(N,N-diethylamino)benzyl chloride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 24h;
94%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

4-Benzyloxyphenol
103-16-2

4-Benzyloxyphenol

1-((4-(2-(allyloxy)ethoxy)phenoxy)methyl)benzene
1354967-78-4

1-((4-(2-(allyloxy)ethoxy)phenoxy)methyl)benzene

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In dichloromethane at 20℃; Mitsunobu reaction;93%
With di-isopropyl azodicarboxylate; triphenylphosphine In dichloromethane at 20℃;71%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

5-hexenyl methanesulfonate
64818-36-6

5-hexenyl methanesulfonate

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water at 0 - 20℃; for 1h;93%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

para-thiocresol
106-45-6

para-thiocresol

A

di(p-tolyl) disulfide
103-19-5

di(p-tolyl) disulfide

B

[3-(4-methylphenylthio)propoxy]ethanol

[3-(4-methylphenylthio)propoxy]ethanol

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In neat (no solvent) at 20℃; for 5h; Green chemistry; regioselective reaction;A n/a
B 93%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

4-Nitrophthalonitrile
31643-49-9

4-Nitrophthalonitrile

5-allyoxyethyl phthalonitrile

5-allyoxyethyl phthalonitrile

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 72h; Inert atmosphere;93%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

2-(but-3-en-1-yloxy)ethyl nitrate

2-(but-3-en-1-yloxy)ethyl nitrate

Conditions
ConditionsYield
With nitric acid; acetic anhydride In dichloromethane at -50 - 20℃; for 5.5h;92%
ethylene glycol monoallyl ether
111-45-5

ethylene glycol monoallyl ether

2-(prop-3-en-1-yloxy)ethyl nitrate
75988-50-0

2-(prop-3-en-1-yloxy)ethyl nitrate

Conditions
ConditionsYield
With nitric acid; acetic anhydride In dichloromethane at -50 - 20℃; for 4.5h;92%

111-45-5Related news

Spectroscopic and PM5 semiempirical study of a new lasalocid ester with 2-Allyloxyethanol (cas 111-45-5) and its complexes with monovalent cations08/20/2019

A new ester of lasalocid with 2-allyloxyethanol (Las9) has been synthesised and its ability to form complexes with Li+, Na+, K+, Rb+ and Cs+ cations has been studied by ESI mass spectrometry as well as 1H, 13C NMR and FT-IR spectroscopic methods. The ESI-MS spectra indicate that Las9 forms stabl...detailed

111-45-5Relevant articles and documents

9-(2-Aryloxyethyl) derivatives of adenine - A new class of non-nucleosidic antiviral agents

Petrov,Ozerov,Novikov,Pannecouque,Balzarini,De Clercq

, p. 1218 - 1226 (2003)

New 9-(aryloxyalkyl) derivatives of adenine have been prepared by alkylation of adenine with tosylates, bromides, and α-chloro ethers containing terminal aromatic fragments in anhydrous DMF in the presence of potassium carbonate. The compounds of the 9-(2-phenoxyethyl)adenine series appear to be highly reactive against cytomegaloviruses of mankind in vitro, while derivatives of 9-(2-benzyloxyethyl)adenine demonstrate anti-HIV-1 activity. Compounds with shorter or longer chains, and also compounds which do not have aromatic fragments at the ends of the chains, do not possess antiviral activity.

-

Bertrand,M.P. et al.

, p. 1365 - 1372 (1979)

-

Salt- and pH-Triggered Helix-Coil Transition of Ionic Polypeptides under Physiology Conditions

Yuan, Jingsong,Zhang, Yi,Sun, Yue,Cai, Zhicheng,Yang, Lijiang,Lu, Hua

, p. 2089 - 2097 (2018)

Controlling the helix-coil transition of polypeptides under physiological conditions is an attractive way toward smart functional materials. Here, we report the synthesis of a series of tertiary amine-functionalized ethylene glycol (EGx)-linked polypeptide electrolytes with their secondary structures tunable under physiological conditions. The resultant polymers, denoted as P(EGxDMA-Glu) (x = 1, 2, and 3), show excellent aqueous solubility (>20 mg/mL) regardless of their charge states. Unlike poly-l-lysine that can form a helix only at pH above 10, P(EGxDMA-Glu) undergo a pH-dependent helix-coil switch with their transition points within the physiological range (pH ~5.3-6.5). Meanwhile, P(EGxDMA-Glu) exhibit an unusual salt-induced helical conformation presumably owing to the unique properties of EGx linkers. Together, the current work highlights the importance of fine-tuning the linker chemistry in achieving conformation-switchable polypeptides and represents a facile approach toward stimuli-responsive biopolymers for advanced biological applications.

Chain extender as well as preparation method and application thereof

-

Paragraph 0038; 0041; 0043; 0046; 0048; 0051, (2022/01/20)

The invention relates to a chain extender. The chain extender is 3-(2-(2, 3-dihydroxy propyl) sulfo) ethyoxyl) propyl 3-(3-(tert-butyl)-4-hydroxy-5-methyl phenyl) propionate (GL), and the structural formula of the chain extender is shown in the specification. The prepared chain extender GL has an excellent toughening effect; the elongation at break of a polyurethane elastomer prepared from the GL reaches 1531.1594%, the toughness reaches 12.315% MJ/m , the repairing efficiency reaches 103.62% after the polyurethane elastomer is repaired for 6 h at the normal temperature, and the repairing efficiency reaches 125.53% after the polyurethane elastomer is repaired for 2 h at the temperature of 80 DEG C. The prepared chain extender GL can be compounded with other reinforced chain extenders so as to be used, and the tensile strength and toughness of the polyurethane elastomer are further improved synergistically.

Structurally Simple Benzyl-Type Photolabile Protecting Groups for Direct Release of Alcohols and Carboxylic Acids

Wang, Pengfei,Lu, Wenya,Devalankar, Dattatray A.,Ding, Zhenying

supporting information, p. 2114 - 2117 (2015/05/13)

Structurally simple benzyl-type photolabile protecting groups (PPGs) have been developed to release alcohols and carboxylic acids. Release of two substrates from one PPG chromophore has also been accomplished. (Chemical Equation Presented).

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