111465-42-0

Basic information

• Product Name: (3S,4R,9R)-9-ethyl-3-(hydroxymethyl)-1,7-dioxaspiro[5.5]undecan-4-ol
• CAS NO: 111465-42-0
• Molecular Formula: C₁₂H₂₂O₄
• Molecular Weight: 230.3007
• Mol File: 111465-42-0.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 397.4°C at 760 mmHg
• Flash Point: 194.1°C
• Density: 1.15g/cm³
• Vapor Pressure: 5.77E-08mmHg at 25°C
• Refractive Index: 1.514
• CAS DataBase Reference: (3S,4R,9R)-9-ethyl-3-(hydroxymethyl)-1,7-dioxaspiro[5.5]undecan-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R,9R)-9-ethyl-3-(hydroxymethyl)-1,7-dioxaspiro[5.5]undecan-4-ol(111465-42-0)
• EPA Substance Registry System: (3S,4R,9R)-9-ethyl-3-(hydroxymethyl)-1,7-dioxaspiro[5.5]undecan-4-ol(111465-42-0)

Safety Data

• Hazardous Substances Data: 111465-42-0(Hazardous Substances Data)

Upstream product

• 73805-43-3 4-Ethyl-5-hydroxypentanoic acid lactone 
• 922167-76-8 2-Vinyl-propane-1,3-diol 
• 91704-00-6 C₁₉H₂₆O₄ 
• 121363-52-8 (3S*,6R*,9R*)-3-<(t-butyldimethyl)siloxy>methyl-9-ethyl-1,7-dioxaspiro<5.5>undec-4-ene 
• 121363-53-9 (3S*,4S*,5S*,6R*,9R*)-3-<(t-butyldimethyl)siloxy>methyl-5-chloro-9-ethyl-1,7-dioxaspiro<5.5>undecan-4-ol 
• 911807-03-9 2-(4-hydroxy-3-hydroxymethylbut-1-ynyl)-5-ethyl-2-methoxytetrahydropyran 
• 121363-50-6 2,2-diethyl-5-(6-ethyl-7-hydroxy-3-oxohex-1-yne)-1,3-dioxane 
• 121363-48-2 (3S*,6R*,9R*)- and (3R*,6R*,9R*)-9-ethyl-3-hydroxymethyl-1,7-dioxaspiro<5.5>undec-4-ene 
• 121363-54-0 (3S*,4R*,6R*,9R*)-3-<(t-butyldimethyl)siloxy>methyl-9-ethyl-1,7-dioxaspiro<5.5>undecan-4-ol 
• 132775-87-2 (E)-(R)-2-Ethyl-6-trimethylsilanyl-hex-4-en-1-ol 
• 132775-91-8 (2R)-2-ethyl-6-(trimethylsilyl)-4-hexyn-1-ol 
• 132775-88-3 (5R)-5-ethyl-2-methylenetetrahydropyran 
• 132775-92-9 (R)-(-)-2-ethylhex-5-en-1-ol 
• 132775-95-2 (4S,6R,9R)/(4R,6S,9R)-9-ethyl-4-hydroxy-3-(hydroxymethyl)-1,7-dioxaspiro<5.5>undec-2-ene 

Downstream Products

• 83720-10-9 talaromycin C 
• 83720-10-9 talaromycin E 
• 83720-10-9 talaromycin F 
• 83720-10-9 talaromycin B 
• 83720-10-9 talaromycin G 
• 83720-10-9 (-)-talaromycin B 
• 83720-10-9 talaromycin A 
• 106763-16-0 talaromycin A 12-(3',5'-dinitrobenzoate) 
• 106763-16-0 3-(9-ethyl-4-hydroxy-1,7-dioxaspiro<5.5>undecyl)methyl (3',5'-dinitro)benzoate 
• 83780-27-2 (-)-Talaromycin B 
• 113195-31-6 C₂₆H₂₆N₄O₁₄ 
• 106763-16-0 3-(9-ethyl-4-hydroxy-1,7-dioxaspiro<5.5>undecyl)methyl (3',5'-dinitro)benzoate 
• 106763-16-0 3-(9-ethyl-4-hydroxy-1,7-dioxaspiro<5.5>undecyl)methyl (3',5'-dinitro)benzoate 

Relevant articles and documents

Talaromycins: Applications of Homonuclear Spin Correlation Maps to Structure Assignements

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Enantioselective Total Synthesis of the Mycotoxin (-)-Talaromycin B by a Hetero Diels-Alder Reaction

(-)-Talaromycin B was formed in an overall yield of 5 percent in nine steps via a hetero Diels-Alder reaction of the exocyclic vinyl ether 3 and methyl O-benzoyldiformylacetate (4) as the key transformation.The enantiomerically pure vinyl ether 3 was prep

SYNTHESIS OF (-)-TALAROMYCINS A AND B

Highly enantiomerically pure (-)-talaromycins A and B undecane> were synthesized starting from chiral building blocks of microbial origin.