111873-52-0Relevant articles and documents
Sterically demanding unsymmetrical diaryl-λ3-iodanes for electrophilic pentafluorophenylation and an approach to α-pentafluorophenyl carbonyl compounds with an all-carbon stereocenter
Matsuzaki, Kohei,Okuyama, Kenta,Tokunaga, Etsuko,Shiro, Motoo,Shibata, Norio
, p. 233 - 237 (2014)
A sterically demanding unsymmetrical pentafluorophenyl-triisopropylphenyl-λ3-iodane was developed as an effective reagent for the electrophilic pentafluorophenylation of various β-keto esters and a β-keto amide. 17 examples of α-pentafluorophen
Fluorine-containing diaryliodonium salt and application thereof
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, (2017/01/02)
The invention relates to fluorine-containing diaryliodonium salt as well as a preparation method and an application thereof. The fluorine-containing diaryliodonium salt has a structure represented as a formula I and is taken as an arylation reagent. The fluorine-containing diaryliodonium salt has the advantages that the preparation is easy, when the fluorine-containing diaryliodonium salt is applied to an arylation reaction, the arylation reaction condition is relatively mild, the selectivity of an arylation product is good and the like; in the formula I shown in the specification, R1 represents an aromatic ring group or a heteroaromatic ring group or represents a substituted aromatic ring group or a substituted heteroaromatic ring group, and Y represents a univalent organic or inorganic acid radical anion.
NOVEL PENTAFLUOROPHENYL HYPERVALENT IODINE REAGENTS
Moriarty, Robert M.,Penmasta, Raju,Prakash, Indra
, p. 877 - 880 (2007/10/02)
The novel C6F5I(OH)OTs has been synthesized and shown to undergo ligand exchange with C6H5I,iodonium ylide formation with dimedone and iodonium salt formation with anisole.