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114133-26-5

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114133-26-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114133-26-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,1,3 and 3 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 114133-26:
(8*1)+(7*1)+(6*4)+(5*1)+(4*3)+(3*3)+(2*2)+(1*6)=75
75 % 10 = 5
So 114133-26-5 is a valid CAS Registry Number.

114133-26-5Upstream product

114133-26-5Downstream Products

114133-26-5Relevant articles and documents

Preparation and Properties of, and Reactions with Metal-Containing Heterocycles, LX. - Investigations on the Preparation and Structure of Phosphidomolybdates

Lindner, Ekkehard,Staengle, Michael,Hiller, Wolfgang,Fawzi, Riad

, p. 1421 - 1426 (2007/10/02)

Substitution of CO in HCO (1) = (η5-C5H5)Mo(CO)2> by the secondary phosphanes R2PH results in the formation of the hydrido complexes HPR2H (2a-c) a), C6H11 (b), C6H5 (c)>.Reaction of 2a-c with Li affords the lithium salts LiPR2H> (3a-c) with elimination of H2.Only 3a, c react with n-BuLi to give the phosphidomolybdates Li2PR2> (4a,c).These are also obtained in a straightforward way from 2a, c and n-BuLi.Upon the action of the dihalometal complexes X2 on 4c, the phosphido-bridged heterobimetallic complexes -μ-PR2- = Fe(CO)4 (5c), Ru(CO)4 (6c), (η5-C5H5)CoCO (7c)> are obtained.According to an X-ray structural analysis. 5a crystallizes in the monoclinic space group P21/n with Z = 4.

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