115022-91-8

Basic information

• Product Name: N--N'-phenylbenzamidine
• CAS NO: 115022-91-8
• Molecular Weight: 386.561
• Mol File: 115022-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N--N'-phenylbenzamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N--N'-phenylbenzamidine(115022-91-8)
• EPA Substance Registry System: N--N'-phenylbenzamidine(115022-91-8)

Safety Data

• Hazardous Substances Data: 115022-91-8(Hazardous Substances Data)

Upstream product

• 14933-91-6 N-phenyl-benzenesulphenamide 
• 100-47-0 benzonitrile 
• 110-83-8 cyclohexene 

Relevant articles and documents

Boron Trifluoride-Promoted Reaction of Benzenesulphenanilides with Alkenes in Acetonitrile and Benzonitrile: Amidino- and Amido-sulphenylation of Alkenes

Benzenesulphenanilides (1) react at room temperature with alkenes in acetonitrile or benzonitrile in the presence of boron trifluoride-diethyl ether to give amidino sulphides (5; R=Me, Ph) in fair to good yields together with varying amounts of amido sulphides (7; R=Me, Ph) and arylamino sulphides (4), whereas at 100 deg C and in the presence of water 4'-nitrobenzenesulphenanilide affords amido sulphides (7; R=Me, Ph) as the main products.With cyclohexene a high selectivity for trans-addition is observed.With terminal alkenes the terminal sulphides are produced with high regioselectivity.The findings are consistent with a mechanism involving intermediacy of episulphonium ions (3) which result from alkene attack at the sulphur atom of an anilide-BF3 complex.