116608-28-7

Basic information

• Product Name: 2-(2-bromoprop-2-enyloxy)cyclohexan-1-ol
• Synonyms: 2-(2-bromoprop-2-enyloxy)cyclohexan-1-ol
• CAS NO: 116608-28-7
• Molecular Weight: 235.121
• Mol File: 116608-28-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(2-bromoprop-2-enyloxy)cyclohexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-bromoprop-2-enyloxy)cyclohexan-1-ol(116608-28-7)
• EPA Substance Registry System: 2-(2-bromoprop-2-enyloxy)cyclohexan-1-ol(116608-28-7)

Safety Data

• Hazardous Substances Data: 116608-28-7(Hazardous Substances Data)

Upstream product

• 598-19-6 2-bromoallyl alcohol 
• 107-19-7 propargyl alcohol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 513-31-5 2-bromoallyl bromide 

Downstream Products

• 94532-07-7 α-(prop-2-enyloxy)cyclohexanone 
• 81189-45-9 2-(prop-2-enyloxy)cyclohexan-1-ol 
• 94532-06-6 2-(2-bromoprop-2-enyloxy)cyclohexan-1-one 

Relevant articles and documents

Intramolecular Free Radical Cyclisations onto Enol Ethers. A General Synthesis of α-Alkyl-β-oxy- and α-Methylene-β-oxy-γ-butyrolactones

Radical cyclisation of the enol ether bromoacetals (26), (28a-c), (29), and (37) in the presence of tributylstannane, produces precursors to the β-oxy-γ-butyrolactones (33), (34a-c), (35), and the α-methylene-β-oxy-γ-butyrolactone (39) in high overall yields.By contrast, treatment of (26) and (28a-b) with the cobalt(I) reagent derived from bis(dimethylglyoximato)(pyridine)cobalt(III) chloride (40), followed by oxidation of the intermediates (43) leads to the corresponding unsaturated β-oxy-γ-butyrolactones (42).