116632-38-3Relevant articles and documents
Synthesis of shape-persistent macrocycles with three 1,8-diazaanthracene units and their packing in the single crystal
Li, Ming,Klaerner, Frank-Gerrit,Sakamoto, Junji,Schlueter, A. Dieter
, p. 13348 - 13354 (2013)
The synthesis of four shape-persistent macrocycles with three 1,8-diazaanthracene units each is reported (2,3 a-3 c). For two of them single crystals could be obtained and the structures in the crystal be solved. The structures reveal that macrocycle 2 se
A practical and general ipso iodination of arylboronic acids using N-iodomorpholinium iodide (NIMI) as a novel iodinating agent: mild and regioselective synthesis of aryliodides
Tale,Toradmal,Gopula
, p. 84910 - 84919 (2015/10/28)
A mild and efficient protocol for the ipso-iodination of aryl boronic acids using N-iodomorpholinium iodide (NIMI) generated in situ from morpholine and molecular iodine as a novel iodinating agent has been developed. The addition of a catalytic amount of copper iodide found to promote rate enhancement of the iodination reaction and dramatic increase in the yield depending upon the nature of the boronic acid was observed. The mechanistic study revealed that depending upon the nature of the substrate, either the classical ipso substitution or copper catalysed iododeborylation pathway overall dominates the present iodination reaction. The features such as mild reaction conditions, operational simplicity, high to excellent yields, excellent functional group compatibility and low catalyst loading make this method potentially useful in organic synthesis.
INHIBITORS OF IKK-BETA SERINE-THERONINE PROTEIN KINASE
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, (2011/04/13)
Cyclopentyl(2S,4E)-2-amino-5-{3-[4-carbamoyl-5(carbamoylamino)-2-thienyl]phenyl}pent-4-enoate; Cyclopentyl 5-{3-[4-carbamoyl-5-(carbamoylamino)-2-thienyl]phenyl}-L-norvalinate; Cyclopentyl(2S,4E)-2-amino-5-{3-[4-carbamoyl-5-(carbamoylamino)-2-thienyl]-5-m
INHIBITORS OF IKK-β SERINE-THREONINE PROTEIN KINASE
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, (2009/12/05)
Cyclopentyl (2S,4E)-2-amino-5-{3-[4-carbamoyl-5 (carbamoylamino)-2-thienyl]phenyl}pent-4-enoate; Cyclopentyl 5-{3-[4-carbamoyl-5-(carbamoylamino)-2-thienyl]phenyl}-L-norvalinate; Cyclopentyl (2S,4E)-2-amino-5-{3-[4-carbamoyl-5-(carbamoylamino)-2-thienyl]-
An easy and multigram-scale synthesis of versatile AA- and AB-type w-terphenylenes as building blocks for kinked polyphenylenes
Kissel, Patrick,Breitier, Simon,Reinmueller, Viktoria,Lanz, Patrick,Federer, Lukas,Schlueter, A. Dieter,Sakamoto, Junji
supporting information; experimental part, p. 2953 - 2955 (2009/11/30)
A set of m-terphenylenes having a readily functionalizable hydroxy group as well as either symmetric AA-type or unsymmetric AB-type halide termini have been prepared on a several-gram scale. The synthesis was carried out on the basis of the Suzuki-Miyaura