Welcome to LookChem.com Sign In|Join Free

CAS

  • or

117256-61-8

IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

117256-61-8 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 117256-61-8 Structure

  • Basic information

    1. Product Name: IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4)
    2. Synonyms: IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4)
    3. CAS NO:117256-61-8
    4. Molecular Formula:
    5. Molecular Weight: 997.535
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 117256-61-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4)(CAS DataBase Reference)
    10. NIST Chemistry Reference: IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4)(117256-61-8)
    11. EPA Substance Registry System: IrCl(CO)(PPh3)2(OSNSO2C6H4Me-4)(117256-61-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 117256-61-8(Hazardous Substances Data)

117256-61-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 117256-61-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,2,5 and 6 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 117256-61:
(8*1)+(7*1)+(6*7)+(5*2)+(4*5)+(3*6)+(2*6)+(1*1)=118
118 % 10 = 8
So 117256-61-8 is a valid CAS Registry Number.

117256-61-8Relevant articles and documents

The coordination chemistry of iminooxosulphuranes VI. Factors affecting coordination geometry in complexes of tosyliminooxosulphurane

Herberhold, Max,Hill, Anthony F.

, p. 195 - 206 (1990)

The complexes (M = Ru, Rh, Os, Ir) have been prepared from the 16-electron complex or the corresponding tris(phosphine) compounds .The sulphinylamine cumulene adopts one of three possible bonding geometries (pyramidal, or coplanar through sulphur, or ?-coordination through sulphur and nitrogen).The preference for a particular mode in a given complex is discussed in terms of metal electron density, d-orbital occupancy, oxidation state and frontier orbital symmetry.Treatment of the complex (prepared from tosyliminooxosulphurane and ) with carbon monoxide results in a rearrangement of the ?-bond cumulene in the precursor to a pyramidally bound ligand in the CO adduct .

Novel Synthetic Routes to Disulphur and Disulphur Monoxide Ligands: Nucleophilic Attack at Co-ordinated Imino-oxo-λ4-sulphanes

Herberhold, Max,Hill, Anthony F.

, p. 2027 - 2032 (2007/10/02)

The reactions of and with oxo-4-tosylimino-λ4-sulphane (4-MeC6H4SO2NSO) lead quantitatively to the adducts Cl(PPh3)2(4-MeC6H4SO2NSO)> = Os(NO) or Ir(CO)> which in turn are hydrolysed to the corresponding sulphur dioxide complexes Cl(PPh3)2(SO2)>.The iridium compound reacts cleanly with hydrogen sulphide to provide the disulphur monoxide complex whilst with hydrosulphide leads to the disulphur complex which may be oxidised to the corresponding S2O complex with 3-chloroperbenzoic acid.Alternatively, is accessible via the reaction of with cyclo-octasulphur.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 117256-61-8