1177249-19-2

Basic information

• Product Name: (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene
• CAS NO: 1177249-19-2
• Molecular Weight: 425.377
• Mol File: 1177249-19-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene(1177249-19-2)
• EPA Substance Registry System: (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene(1177249-19-2)

Safety Data

• Hazardous Substances Data: 1177249-19-2(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 67251-69-8 N,N-dimethylaminoferrocene 
• 109-63-7 boron trifluoride diethyl etherate 
• 16523-54-9 chlorodicyclohexylphosphane 
• 1262899-10-4 (S)-(-)-2-dicyclohexylphosphinothioyl-1-dimethylaminoferrocene 

Downstream Products

• 1177249-23-8 dichloro(2-dicyclohexylphosphino-1-dimethylaminoferrocene-κN,P)platinum(II) 
• 1262899-37-5 (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene iridium(cyclooctadiene) chloride 

Relevant articles and documents

Asymmetric hydrogenation of alkenes with planar chiral 2-phosphino-1- aminoferrocene-iridium(I) complexes

The first highly enantioenriched and enantiopure planar chiral 2-phosphino-1-aminoferrocene ligands and their Ir(COD)BArF complexes are reported. The ligands display bidentate coordination behavior towards iridium, as indicated by trends in 31P and 1H NMR spectra of the phosphine moieties and the α to nitrogen substituents of the amines. All of the new complexes showed good reactivity as catalysts in promoting asymmetric hydrogenation of several prochiral alkenes, with enantioselectivities up to 92%. Iridium complexes of dimethylaminoferrocene derivatives containing P-Ar groups [PPh2 and P(o-tol)2] gave the highest levels of asymmetric induction.