118133-43-0

Basic information

• Product Name: benzyl ether of 6-isopropenyl-3,9-dimethyldeca-2,8-dien-1-ol
• CAS NO: 118133-43-0
• Molecular Weight: 312.495
• Mol File: 118133-43-0.mol

Chemical Properties

• CAS DataBase Reference: benzyl ether of 6-isopropenyl-3,9-dimethyldeca-2,8-dien-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl ether of 6-isopropenyl-3,9-dimethyldeca-2,8-dien-1-ol(118133-43-0)
• EPA Substance Registry System: benzyl ether of 6-isopropenyl-3,9-dimethyldeca-2,8-dien-1-ol(118133-43-0)

Safety Data

• Hazardous Substances Data: 118133-43-0(Hazardous Substances Data)

Upstream product

• 35189-96-9 3-methyl-2-butenylmagnesium chloride 
• 118133-42-9 (2E)-2-(1-benzyloxy-3,7-dimethylocta-2,7-dien-6-yloxy)benzothiazole 

Relevant articles and documents

Regioreversed Nucleophilic Substitution of 2-(Allyloxy)benzothiazole by Allylic Grignard Reagents. A Regioselective Synthesis of 1,5-Dienes

2-(Allyloxy)benzothiazoles react with allylic organomagnesium compounds in the presence of copper bromide to give 1,5-dienes.The C-C coupling occurs almost exclusively in a head-to-tail fashion.Contrary to this the same electrophiles, when complexed with copper(I) bromide before the addition of the allylic Grignard reagents, give only 1,5-dienes derived from head-to-head coupling process.The change in the selectivity is probably due to the co-ordinative effects of the substrate towards the organometallic species.