1188-63-2

Basic information

• Product Name: 4-Heptanone oxime
• Synonyms: 4-Heptanone oxime;Dipropyl ketone oxime;Dipropyl ketoxime
• CAS NO: 1188-63-2
• Molecular Formula: C₇H₁₅NO
• Molecular Weight: 129.2001
• Mol File: 1188-63-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 207.8°Cat760mmHg
• Flash Point: 109.6°C
• Appearance: /
• Density: 0.88g/cm³
• Vapor Pressure: 0.0887mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: 4-Heptanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Heptanone oxime(1188-63-2)
• EPA Substance Registry System: 4-Heptanone oxime(1188-63-2)

Safety Data

• Hazardous Substances Data: 1188-63-2(Hazardous Substances Data)

Usage

General Description

4-Heptanone oxime is a chemical compound with the formula C7H15NO. It is an oxime derivative of 4-heptanone, which is a solvent and an intermediate in the production of pharmaceuticals and other organic compounds. 4-Heptanone oxime is commonly used in the synthesis of various organic compounds and as a reagent in chemical reactions. It is also known for its ability to inhibit the formation of advanced glycation end products, which are associated with aging and various diseases. The compound is typically handled and stored in a controlled environment due to its potential reactivity and toxicity. Overall, 4-heptanone oxime plays a crucial role in the field of organic and pharmaceutical chemistry.

InChI:InChI=1/C7H15NO/c1-3-5-7(8-9)6-4-2/h9H,3-6H2,1-2H3

Upstream product

• 682-29-1 4-chloro-4-nitrosoheptane 
• 123-19-3 4-heptanone 
• 142-82-5 n-heptane 
• 64-17-5 ethanol 
• 60-29-7 diethyl ether 
• 7803-49-8 hydroxylamine 
• 97031-82-8 bis(4-nitrosoheptane) 

Downstream Products

• 53442-84-5 C₁₆H₂₂ClNO₃ 
• 53443-47-3 C₁₅H₁₈Cl₃NO₃ 
• 53443-16-6 C₁₆H₂₁Cl₂NO₃ 
• 53442-95-8 C₁₇H₂₄ClNO₃ 
• 161837-48-5 O-cinnamyl 4-heptanone oxime 
• 5129-73-7 N-propylbutyrylamide 
• 150967-34-3 4-heptylideneaminoester of 4-(4,6-dimethoxypyrimidin-2-yloxy)-2-phenylfuran-3-carboxylic acid 
• 161330-97-8 O-((E)-3-Phenyl-allyl)-N-(1-propyl-butyl)-hydroxylamine 
• 53443-34-8 C₁₅H₁₉Cl₂NO₃ 
• 16751-59-0 4-heptylamine 
• 123-19-3 4-heptanone 
• 71350-25-9 di-n-propyl ketone oxime O-allyl ether 
• 89796-76-9 4,4-dichloroheptane 

Relevant articles and documents

Selective Production of Hydrazine by a Catalytic Oxidation Process over Ti-, V-, Ti-V- and Ti-B-Silicalites

A simple catalytic process to obtain hydrazine by oxidation of ketone-NH3 system by H2O2 is reported; Ti-, V-, Ti-V- and Ti-B-silicalites of MFI structure are found to be active as catalysts in this oxidation reaction.

Copper-catalyzed synthesis of thiazol-2-yl ethers from oxime acetates and xanthates under redox-neutral conditions

A novel copper-catalyzed annulation of oxime acetates and xanthates for the synthesis of thiazol-2-yl ethers with remarkable regioselectivity has been developed. Various oxime acetates, whether derived from aryl ketones or alkyl ketones, or natural product cores are suitable for this conversion. Unique dihydrothiazoles were also obtained when both reaction sites were methine. Mechanistic studies indicated that imino copper(iii) intermediates were involved. In addition, this protocol proceeded under redox-neutral conditions and did not require additives or ligands.

A mild synthesis of vinyl halides and gem-dihalides using triphenyl phosphite-halogen-based reagents

A new application of (PhO)3P-halogen-based reagents to the synthesis of vinyl halides and gem-dihalides is described. Vinyl halides were prepared in good to excellent yields from enolizable ketones, whereas aldehydes afforded the corresponding gem-dihalides. The halogenation proceeded smoothly under mild conditions.