1203507-22-5Relevant articles and documents
Isothiourea-catalyzed enantioselective carboxy group transfer
Joannesse, Caroline,Johnston, Craig P.,Concellon, Carmen,Simal, Carmen,Philp, Douglas,Smith, Andrew D.
supporting information; experimental part, p. 8914 - 8918 (2010/02/28)
Transferable skills: Enantiomerically pure isothioureas promote the 0-to C-carboxyl group transfer of oxazolyl carbonates with excellent levels of enantiocontrol (see scheme). The origin of the enantioselectivity of this process was probed mechanistically and rationalized computationally.