121614-06-0

Basic information

• Product Name: Methyl (3R,4S)-3--4,5-(isopropylidenedioxy)-pentanoate
• CAS NO: 121614-06-0
• Molecular Weight: 423.625
• Mol File: 121614-06-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl (3R,4S)-3--4,5-(isopropylidenedioxy)-pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (3R,4S)-3--4,5-(isopropylidenedioxy)-pentanoate(121614-06-0)
• EPA Substance Registry System: Methyl (3R,4S)-3--4,5-(isopropylidenedioxy)-pentanoate(121614-06-0)

Safety Data

• Hazardous Substances Data: 121614-06-0(Hazardous Substances Data)

Upstream product

• 15186-48-8 2,3-isopropylidene-glyceraldehyde 
• 77086-38-5 ketene t-butyldimethylsilyl methyl acetal 
• 91190-38-4 N-benzyl-2,3-O-isopropylidene-D-glyceraldehyde nitrone 
• 622-30-0 N-benzyl hydroxylalmine 

Downstream Products

• 126569-19-5 methyl (3R,4S)-3-benzoylamino-4,5-(isopropylidenedioxy)pentanoate 
• 121701-19-7 (3R,4S)-5-acetoxy-3-benzoylamino-4-pentanolide 
• 87411-81-2 methyl (3R,4S)-3-butylamino-4,5-(isopropylidenedioxy)pentanoate 

Relevant articles and documents

Ketene Silyl Acetal Chemistry; Diastereofacial Selectivity of 1,3-Addition of Chiral Nitrones

The reaction of dimethyl-t-butylsiloxy-1-methoxyethene (1a) with the N-benzylnitrone (3a) produced the syn-1,3-adduct (4a) predominantly, while the reaction of dimethyl-t-butylsiloxy-1-t-butoxyethene (1b) with the N-diphenylmethylnitrone (3d) gave the ant