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122180-10-3

N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 122180-10-3 Structure

  • Basic information

    1. Product Name: N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT
    2. Synonyms: N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT;N-Fluoroquinuclidinium triflate, 1-Fluoro-1-azoniabicyclo[2.2.2]octane trifluoromethanesulphonate
    3. CAS NO:122180-10-3
    4. Molecular Formula: C8H13F4NO3S
    5. Molecular Weight: 279.2523328
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 122180-10-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT(CAS DataBase Reference)
    10. NIST Chemistry Reference: N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT(122180-10-3)
    11. EPA Substance Registry System: N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANESULPHONAT(122180-10-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 122180-10-3(Hazardous Substances Data)

122180-10-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 122180-10-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,1,8 and 0 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 122180-10:
(8*1)+(7*2)+(6*2)+(5*1)+(4*8)+(3*0)+(2*1)+(1*0)=73
73 % 10 = 3
So 122180-10-3 is a valid CAS Registry Number.

122180-10-3Downstream Products

122180-10-3Relevant articles and documents

N-HALOGENO-COMPOUNDS. PART 10. N-FLUOROQUINUCLIDINIUM TRIFLATE

Banks, Ronald Eric,Sharif, Iqbal

, p. 297 - 300 (1988)

Direct fluorination of quinuclidine at ca. -33 deg C in acetonitrile containing lithium trifluoromethanesulphonate (triflate) gives N-fluoroquinuclidinium triflate (2) in excellent yield.Similar fluorination of quinuclidine in trichlorofluoromethane at -78 deg C, followed by treatment of the resultant N-fluoroquinuclidinium fluoride (1) with trimethylsilyl triflate, also yields the new triflate, but in somewhat lower yield (80percent).N-Fluoroquinuclidinium triflate (2) is much more convenient to use as an electrophilic fluorinating agent than the fluoride (1) owing to its non-hygroscopic nature.

N-Halogeno compounds. Part 13. N-Fluoroquinuclidinium salts - synthesis and use as electrophilic fluorinating agents

Banks, Ronald Eric,Sharif Iqbal

, p. 207 - 214 (1991)

A convenient one-pot method has been developed for the preparation of the easily handled electrophilic fluorinating agent N-fluoroquinuclidinium triflate from quinuclidine, lithium triflate and fluorine.The corresponding trifluoroacetate, heptafluoro-n-butyrate and tetrafluoroborate salts were procured in a two-step fashion by adding the appropriate sodium salts to acetonitrile solutions of N-fluoroquinuclidinium fluoride.Site-specific fluorination of phenylmagnesium bromide (to PhF), diethyl sodio(phenyl)malonate , 2-nitropropan-2-yl-lithium , 1-morpholinocyclohexene >, phenol (to 2- and 4-FC6H4OH + 1,4-F2C6H3OH) and sodium benzenesulphinate (to PhSO2F) was achieved using these new N-fluoroquinuclidinium salts.

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