123313-07-5

Basic information

• Product Name: 1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl-
• CAS NO: 123313-07-5
• Molecular Formula: C4H8N4O
• Molecular Weight: 128.134
• Mol File: 123313-07-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl-(123313-07-5)
• EPA Substance Registry System: 1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl-(123313-07-5)

Safety Data

• Hazardous Substances Data: 123313-07-5(Hazardous Substances Data)

Usage

General Description

1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl- is a chemical compound with a molecular formula C5H7N5O. It is a derivative of the heterocyclic compound triazine, and it contains a triazine ring with a methyl group and an amino group. 1,2,4-Triazin-3(2H)-one, 4-amino-4,5-dihydro-6-methyl- is commonly used in the synthesis of pharmaceuticals and agrochemicals, and it has potential applications in the field of organic chemistry. It is known for its role as a building block in the production of various biologically active compounds. Additionally, it has been studied for its potential pharmacological and biological activities, making it an important compound in the field of medicinal chemistry.

Upstream product

• 119-26-6 (2,4-dinitro-phenyl)-hydrazine 
• 123312-89-0 pymetrozine 

Downstream Products

• 123312-89-0 pymetrozine 

Relevant articles and documents

Electrochemical versus anionic oxygenation of azathymine derivatives

Pymetrozine (1) was converted to hemiaminal 2 in low to moderate yield by trapping its dianion with oxygen followed by reduction with ferrous salts. Pymetrozines 18 and 19 failed to undergo this type of oxygenation. All three pymetrozines were oxidized electrochemically at C5 to methyl hemiaminals 20, 21, and 22, respectively. Hydrolysis of 20 to 2 was accomplished under either acid- or base-catalyzed conditions in excellent yields, whereas the hydrolysis of methyl hemiaminals 21 and 22 was best performed under basic conditions. Soil metabolites of pymetrozine 1, hemiaminals 2 and 3, were prepared on a medium scale and in excellent yields. Linear sweep voltammetry data and conditions for preparative-scale electrochemistry are furnished for the precursory pymetrozines. Complete experimental and spectral data are provided for all new compounds, and the relative merits of anionic versus electrochemical oxidations for alkyl amides are discussed. A cautionary note is provided with the description of the conditions for large-scale anionic oxygenation because of potential explosive hazards.