1237717-79-1Relevant articles and documents
Palladium(II)-catalyzed dicarboxymethylation of chiral allylic alcohols: Chirality transfer affording optically active diesters containing three contiguous chiral centers
Hamed, Othman,Henry, Patrick M.,Becker, Daniel P.
supporting information; experimental part, p. 3514 - 3517 (2010/09/05)
This manuscript describes the extension of Stille's palladium-catalyzed olefin dicarbonylation reaction to chiral allylic alcohols with chirality transfer to afford the corresponding chiral alcohol functionalized with bis-carbomethoxy esters, containing three contiguous chiral centers, in good to excellent diastereoselectivities (78-98%).