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123772-72-5

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123772-72-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 123772-72-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,7,7 and 2 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 123772-72:
(8*1)+(7*2)+(6*3)+(5*7)+(4*7)+(3*2)+(2*7)+(1*2)=125
125 % 10 = 5
So 123772-72-5 is a valid CAS Registry Number.

123772-72-5Downstream Products

123772-72-5Relevant articles and documents

Base-Catalyzed Cyclization of N-Propargylamides to Oxazoles

Nilsson, Bjoern M.,Hacksell, Uli

, p. 269 - 275 (2007/10/02)

The base-catalyzed cyclization of some N-propargylamides to oxazoles has been studied in the presence of sodium hydride and potassium carbonate.The α-arylsubstituted propargylamides 1c-d (Ar = p-OMeC6H4 (1c), C6H5 (1d), and p-O2NC6H4 (1e)) cyclized with markedly higher rates (1e > 1d > 1c) than the unsubstituted and α-methyl substituted propargylamides 1a and 1b.A 1H nmr spectroscopic experiment demonstrated the presence of an allenic intermediate in the potassium carbonate-catalyzed ring closure of 1e.The observed rank order of reactivities correlates well withthe acidities of the respective propargylic hydrogens of the amides and with the ability of the ring closed intermediates to stabilize an oxazole anion.The results demonstrate that the base-catalyzed formation of oxazoles from propargylamides may proceed via an allenic intermediate.

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