124-22-1 Usage
Chemical Properties
Different sources of media describe the Chemical Properties of 124-22-1 differently. You can refer to the following data:
1. white solid
2. Dodecylamine is a solid.
Uses
Different sources of media describe the Uses of 124-22-1 differently. You can refer to the following data:
1. Dodecylamine was used in preparation of novel surfactant copper(II) complexes.Intercalation of dodecylamine into the layer space of kaolinite was investigated. Dodecylamine was investigated as inhibitor of mild steel hydrochloric acid corrosion.
2. Dodecylamine was used in preparation of novel surfactant copper(II) complexes. It is used as a catalyst and template agent in the sol-gel process for the fabrication of monodispersed mesoporous bioactive glass sub-micron spheres.
3. Dodecylamine (DDA) can be used: As a modifier in the preparation of dodecylamine incorporated sodium montmorillonite. It is used as an adsorbent for hexavalent chromium.In the synthesis of DDA-poly(aspartic acid) as a biodegradable water-soluble polymeric material.As an organic surfactant in the synthesis of Sn(IV)-containing layered double hydroxide (LDHs), which can be further used as ion exchangers, absorbents, ion conductors, and catalysts.As a complexing, reducing and capping agent in the synthesis of pentagonal silver nanowires.
General Description
A yellow liquid with an ammonia-like odor. Insoluble in water and less dense than water. Hence floats on water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation or skin absorption. Used to make other chemicals.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
DODECANAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Safety Profile
Poison by intraperitoneal
route. Moderately toxic by ingestion. A severe skin
and eye irritant. When heated to decomposition it
emits toxic fumes of NOx. See also AMINES.
Check Digit Verification of cas no
The CAS Registry Mumber 124-22-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,2 and 4 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 124-22:
(5*1)+(4*2)+(3*4)+(2*2)+(1*2)=31
31 % 10 = 1
So 124-22-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H27N.H2O4S/c1-2-3-4-5-6-7-8-9-10-11-12-13;1-5(2,3)4/h2-13H2,1H3;(H2,1,2,3,4)
124-22-1Relevant articles and documents
Surface properties of Ni/MgO catalysts for the hydrogenation of lauronitrile
Chen, Hui,Xue, Mingwei,Shen, Jianyi
, p. 246 - 255 (2010)
60%Ni/MgO (wt%) catalysts were prepared by the co-precipitation method and the influence of n-butanol treatment was investigated. The results showed that the treatment with n-butanol improved the dispersion and reducibility of supported nickel, resulted in an increase of H2 uptake from 410 to 582 μmol/g, corresponding to an increase of active Ni surface area from 32 to 46 m2/g (increased by 42%). Accordingly, the catalytic activity for the hydrogenation of toluene to methyl cyclohexane was significantly increased. Microcalorimetric adsorption of H2 and CO indicated that the treatment with n-butanol increased the amount of active metal sites on the surface, without the change of electron densities of supported nickel surface. Microcalorimetric adsorption of CO2 and NH3 revealed the strong surface basicity and weak surface acidity for the Ni/MgO catalysts, especially for the reduced ones. The initial heat for the adsorption of acetonitrile was measured to be about 130 kJ/mol on the Ni/MgO catalysts, indicating the strong interaction between acetonitrile and the supported nickel, which might be an important factor determining the activity of nickel for the hydrogenation of aliphatic nitriles. The surface basicity of the Ni/MgO catalysts might play a role in inhibiting the formation of secondary and tertiary amines and therefore improved the selectivity to primary amine during the hydrogenation of lauronitrile to laurylamine. In addition, the Ni/MgO-B catalyst prepared with n-butanol treatment seemed more active for the hydrogenation of lauronitrile.
Broome, F. K.,Ralstone, A. W.,Thornton, M. H.
, p. 67 - 69 (1946)
Direct Enzymatic Synthesis of Fatty Amines from Renewable Triglycerides and Oils
Bevinakatti, Han,Citoler, Joan,Finnigan, William,Turner, Nicholas J.
, (2021/11/30)
Fatty amines represent an important class of commodity chemicals which have broad applicability in different industries. The synthesis of fatty amines starts from renewable sources such as vegetable oils or animal fats, but the process has multiple drawbacks that compromise the overall effectiveness and efficiency of the synthesis. Herein, we report a proof-of-concept biocatalytic alternative towards the synthesis of primary fatty amines from renewable triglycerides and oils. By coupling a lipase with a carboxylic acid reductase (CAR) and a transaminase (TA), we have accomplished the direct synthesis of multiple medium and long chain primary fatty amines in one pot with analytical yields as high as 97 %. We have also performed a 75 mL preparative scale reaction for the synthesis of laurylamine from trilaurin, obtaining 73 % isolated yield.
PROCESS FOR CONVERTING AMIDE TO AMINE
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Page/Page column 22, (2021/06/11)
Provided is a process for converting an amide into an amine comprising hydrogenation of the amide at a temperature not higher than 130°C and a hydrogen pressure not higher than 50 bar in the presence of a supported heterogeneous catalyst preparable by a method comprising depositing vanadium on a supported noble metal catalyst by impregnation.