124306-21-4Relevant articles and documents
(2+1) CYCLOADDITION OF CHLORO(PHENYLTHIO)CARBENE TO VINYL SILANES. A FACILE SYNTHESIS OF HIGHLY FUNCTIONALIZED CYCLOPROPANES
Schaumann, Ernst,Friese, Carsten,Adiwidjaja, Gunadi
, p. 3163 - 3170 (2007/10/02)
Vinylsilanes 1d-h react with chloro(phenylthio)carbene 2 to give functionalized silylcyclopropanes 3 with high Z-stereoselectivity.For 3g, the relative configuration was proven by an X-ray structural analysis.Synthetic modifications of 3 include eliminati