124814-12-6

Basic information

• Product Name: benzyl O-(2-O-benzoyl-3-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 124814-12-6
• Molecular Weight: 1417.66
• Mol File: 124814-12-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl O-(2-O-benzoyl-3-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl O-(2-O-benzoyl-3-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside(124814-12-6)
• EPA Substance Registry System: benzyl O-(2-O-benzoyl-3-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside(124814-12-6)

Safety Data

• Hazardous Substances Data: 124814-12-6(Hazardous Substances Data)

Upstream product

• 18819-89-1 tetrabutylammonium benzoate 

Relevant articles and documents

PREPARATION OF OLIGOSACCHARIDES WITH β-D-MANNOPYRANOSYL AND 2-AZIDO-2-DEOXY-β-D-MANNOPYRANOSYL RESIDUES BY INVERSION AT C-2 AFTER COUPLING

Di- and tri-saccharides with a 2,4,6-tri-O-acetyl-3-O-benzyl-β-D-glucopyranosyl unit were prepared by coupling 1,2,4,6-tetra-O-acetyl-3-O-benzyl-β-D-glucopyranose (1) to suitably, partially benzylated, acceptor sugar derivatives.Deacetylation followed by acetalation gave 3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranosyl derivatives which were treated with N,N'-sulfuryldi-imidazole.The resulting 2-imidazylate group was displaced easily with inversion by benzoate or azide, leading to β-D-mannopyranosyl or 2-azido-2-deoxy-β-D-mannopyranosyl derivatives, respectively.Protected derivatives of β-D-Manp-(1->4)-D-Glc, β-D-Manp-(1->4)-D-Man,β-D-Manp-(1->4)-β-D-Manp-(1->4)-D-Glc, 2-azido-2-deoxy-β-D-Manp-(1->4)-D-Glc, and 2-azido-2-deoxy-β-D-Manp-(1->6)-D-Glc were prepared thus.